Citation: XU Ling-Yun, MEI Xiao, YAN Chun-Hui. Synthesis, Crystal Structure and Photoluminescence Property of Ag(I) with N, N-dimethyl-4-(pyridine-4-yldiazenyl)aniline[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 355-360. doi: 10.14102/j.cnki.0254-5861.2011-0868 shu

Synthesis, Crystal Structure and Photoluminescence Property of Ag(I) with N, N-dimethyl-4-(pyridine-4-yldiazenyl)aniline

1.
a Testing and Analysis Center, Suzhou University, Suzhou 215123, China;
2.
b Department of Life Sciences, Suzhou Industrial Park Institute of Services Outsourcing, Suzhou 215123, China

Received Date: 24 June 2015
Available Online: 4 November 2015
Fund Project:

A 2D plane coordination compound[Ag₂(Dpya)₂^.(NO₃)₂]_n was synthesized and characterized by FT-IR, elemental analysis and TG analysis. The red crystal was obtained via solvent diffusion method at room temperature and is slightly soluble in organic solvents. Its structure was determined by single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group P1 with a = 10.7995(13), b = 7.4748(8), c = 18.364(2) Å, β = 98.916(4)°, V = 1464.5(3) Å³, Z = 2, C₂₆H₂₈Ag₂N₁₀O₆, M_r = 792.32, D_c = 1.302 Mg/m³, F(000) = 792, µ(MoKa) = 1.356 mm^-1, R = 0.0575 and wR = 0.0826. The compound[Ag₂(Dpya)₂^.(NO₃)₂]_n is a two-dimensional structure and there are two kinds of coordination configurations about the Ag atoms in the compound. The Ag(1) center is tetrahedrally coordinated with two O atoms of NO₃^- and two N atoms from the ligand Dpya. Meanwhile, the Ag(2) is five-coordinated by five O atoms from three NO₃^-anions. The Ag centers (Ag(1) and Ag(2)) connect to themselves as well as with each other by the bridging NO₃^-anions. And the coordination compound shows photoluminescence with an emission peak at 530 nm (λ_ex = 450 nm) as the ligand Dpya.
- N,N-dimethyl-4-(pyridine-4-yldiazenyl) aniline,
- Ag compound,
- X-ray diffraction,
- structure,
- photoluminescence
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沈阳化工大学材料科学与工程学院沈阳 110142