Citation: XU Ling-Yun, MEI Xiao, YAN Chun-Hui. Synthesis, Crystal Structure and Photoluminescence Property of Ag(I) with N, N-dimethyl-4-(pyridine-4-yldiazenyl)aniline[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 355-360. doi: 10.14102/j.cnki.0254-5861.2011-0868 shu

Synthesis, Crystal Structure and Photoluminescence Property of Ag(I) with N, N-dimethyl-4-(pyridine-4-yldiazenyl)aniline

1.
a Testing and Analysis Center, Suzhou University, Suzhou 215123, China;
2.
b Department of Life Sciences, Suzhou Industrial Park Institute of Services Outsourcing, Suzhou 215123, China

Received Date: 24 June 2015
Available Online: 4 November 2015
Fund Project:

A 2D plane coordination compound[Ag₂(Dpya)₂^.(NO₃)₂]_n was synthesized and characterized by FT-IR, elemental analysis and TG analysis. The red crystal was obtained via solvent diffusion method at room temperature and is slightly soluble in organic solvents. Its structure was determined by single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group P1 with a = 10.7995(13), b = 7.4748(8), c = 18.364(2) Å, β = 98.916(4)°, V = 1464.5(3) Å³, Z = 2, C₂₆H₂₈Ag₂N₁₀O₆, M_r = 792.32, D_c = 1.302 Mg/m³, F(000) = 792, µ(MoKa) = 1.356 mm^-1, R = 0.0575 and wR = 0.0826. The compound[Ag₂(Dpya)₂^.(NO₃)₂]_n is a two-dimensional structure and there are two kinds of coordination configurations about the Ag atoms in the compound. The Ag(1) center is tetrahedrally coordinated with two O atoms of NO₃^- and two N atoms from the ligand Dpya. Meanwhile, the Ag(2) is five-coordinated by five O atoms from three NO₃^-anions. The Ag centers (Ag(1) and Ag(2)) connect to themselves as well as with each other by the bridging NO₃^-anions. And the coordination compound shows photoluminescence with an emission peak at 530 nm (λ_ex = 450 nm) as the ligand Dpya.
- N,N-dimethyl-4-(pyridine-4-yldiazenyl) aniline,
- Ag compound,
- X-ray diffraction,
- structure,
- photoluminescence
1. [1]
  (1) Takamizawa, S.; Nakata, E.; Akatsuka, T. Magnetic behavior of a 1D molecular-oxygen system included within a transformable single-crystal adsorbent. Angew. Chem. Int. Ed. 2006, 45, 2216-2221.
2. [2]
  (2) Kitagawa, S.; Kitaura, R.; Noro, S. I. Functional porous coordination polymers. Angew. Chem. Int. Ed. 2004, 43, 2375-2379.
3. [3]
  (3) Fan, S. R.; Zhu, L. G. Influence of the reaction conditions on the self-assembly of lead(II) 5-sulfosalicylate coordination polymers with chelating amine ligands. Inorg. Chem. 2006, 45, 7935-7942.
4. [4]
  (4) Wang, P. F.; Wu, X. S.; Wu, Q. Y.; Wang, X. Synthesis, crystal structure and luminescence of a novel cadmium(II) coordination polymer with 5-connected nov net. Chin. J. Struct. Chem. 2011, 30, 1709-1714.
5. [5]
  (5) Yang, Y.; Du, P.; Ma, J. F.; Kan, E. Q.; Liu, B.; Yang, J. A series of metal-organic frameworks based on different salicylic derivatives and 1, 1'-(1, 4-butanediyl)bis(imidazole) ligand: syntheses, structures, and luminescent properties. Cryst. Growth Des. 2011, 11, 5540-5553.
6. [6]
  (6) Chen, X. M.; Liu, G. F. Double-stranded helices and molecular zippers assembled from single-stranded coordination polymers directed by supramolecular interactions. Chem. Eur. J. 2002, 8, 4811-4817.
7. [7]
  (7) Zheng, S. L.; Tong, M. L.; Chen, X. M. Silver(I) hexamethylenetetramine molecular architectures: from self-assembly to designed assembly. Coord. Chem. Rev. 2003, 246, 185-202.
8. [8]
  (8) Wu, G. Y.; Knabe, D. A.; Kim, S. W. Arginine nutrition in neonatal pigs. J. Nutr. 2004, 134, 2783S-2790S.
9. [9]
  (9) Pan, L.; Olson, D. H.; Ciemnolonski, L. R.; Heddy, R.; Li, J. Separation of hydrocarbons with a microporous metal-organic framework. Angew. Chem. Int. Ed. 2006, 45, 616-619.
10. [10]
  (10) Liu, D.; Lang, J. P.; Abrahams, B. F. Highly efficient separation of naphthalene and anthracene in the solid state by a reusable porous coordination polymer through a single-crystal-to-single-crystal transformation. J. Am. Chem. Soc. 2011, 133, 11042-11045.
11. [11]
  (11) Liang, H.; Chen, X. B.; Hu, R. X. Synthesis, crystal structure and spectroscopic properties of a copper(II) complex of the Schiff-base derived from picolinaldehyde N-oxide and 4-aminoantipyridine. Transit. Metal Chem. 2002, 27, 454-457.
12. [12]
  (12) Gebhardt, B.; Vlaho, S.; Fischer, D.; Sewell, A.; Böhles, H. N-carbamylglutamate enhances ammonia detoxification in a patient with decompensated methylmalonic aciduria. Mol. Genet. Metab. 2003, 79, 303-304.
13. [13]
  (13) Li, C. Y.; Chen, X. X.; Zhou, J.; Zhu, Q. Y.; Lei, Z. X.; Zhang, Y.; Dai, J. Cationic main-group metal chalcogenide with a 1-D polymeric structure, [{In(dien)}₂(InTe₄)]·Cl. Inorg. Chem. 2008, 47, 8586-8588.
14. [14]
  (14) Wang, J.; Xu, X. Y.; Ma, W. X.; Xu, R. B.; Tong, Y. P.; Lu, L. D.; Yang, X. J.; Wang, D. Q. Synthesis and structure of a two-dimensional double chain iron(II) L-Trp coordination polymer [Fe(L-trp)₂(HL-trp)₂]_n. Chin. J. of Struc. Chem. 2008, 27, 153-158.
15. [15]
  (15) Wang, Y.; Cheng, P.; Song, Y.; Liao, D. Z.; Yan, S. P. Self-assembly and anion-exchange properties of a discrete cage and 3D coordination networks based on cage structures. Chem. Eur. J. 2007, 13, 8131-8138.
16. [16]
  (16) Sun, X. J.; Xu, L. Y.; Ge, J. F.; Xu, Q. F.; Lu, J. M. Syntheses, crystal structures and properties of six coordination compounds with flexible dps ligand. Polyhedron 2011, 30, 997-1003.
17. [17]
  (17) Xu, L. Y.; Chen, H. X.; Sun, X. J.; Gu, P. Y.; Ge, J. F.; Li, N. J.; Xu, Q. F.; Lu, J. M. Synthesis, structures and optical properties of coordination compounds bearing N, N-dimethyl-4-(pyridin-4-yldiazenyl) aniline. Polyhedron 2012, 35, 7-14.
18. [18]
  (18) Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen 1997.
19. [19]
  (19) Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures. University of Göttingen 1997.
20. [20]
  (20) Beharry, A. A.; Woolley, G. A. Azobenzene photoswitches for biomolecules Chem. Soc. Rev. 2011, 40, 4422-4437.
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