Citation: JU Feng-Yang, LI Yun-Ping, LI Gui-Lian, LIU Guang-Zhen. Syntheses, Crystal Structures, and Magnetic Properties of Cobalt(II) Complexes with 1,1-Cyclohexanediacetic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 404-412. doi: 10.14102/j.cnki.0254-5861.2011-0866 shu

Syntheses, Crystal Structures, and Magnetic Properties of Cobalt(II) Complexes with 1,1-Cyclohexanediacetic Acid

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Received Date: 24 June 2015
Available Online: 7 September 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21571093) (No. 21571093) Technology Innovation Talents in Universities of Henan Province (No. 14HASTIT017) (No. 14HASTIT017)

Two new Co(II) coordination polymers, {[Co₃(Hchda)₂(chda)₂(bpp)₂(H₂O)₂]}_n 1 and {[Co(chda)(bpe)(H₂O)]·3H₂O}_n 2 (H₂chda = 1, 1-cyclohexanediacetic acid, bpp = 1, 3-bis(4-pyridinyl)propane and bpe = 1, 2-bis(4-pyridinyl)ethylene), were hydrothermally synthe-sized and then characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. Complex 1 possesses an infinite metal-organic layer based on triply bridged linear trinuclear subunits and complex 2 exhibits a square (4, 4) grid layer with dangling lateral arms resulting from eight-membered rings above and below the layer. In addition, magnetic properties of complexes 1 and 2 are also given.
- 1,1-cyclohexanediacetic acid,
- hydrothermal synthesis,
- cobalt(II) complex,
- magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142