Citation: JU Feng-Yang, LI Yun-Ping, LI Gui-Lian, LIU Guang-Zhen. Syntheses, Crystal Structures, and Magnetic Properties of Cobalt(II) Complexes with 1,1-Cyclohexanediacetic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 404-412. doi: 10.14102/j.cnki.0254-5861.2011-0866 shu

Syntheses, Crystal Structures, and Magnetic Properties of Cobalt(II) Complexes with 1,1-Cyclohexanediacetic Acid

  • Received Date: 24 June 2015
    Available Online: 7 September 2015

    Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21571093) (No. 21571093) Technology Innovation Talents in Universities of Henan Province (No. 14HASTIT017) (No. 14HASTIT017)

  • Two new Co(II) coordination polymers, {[Co3(Hchda)2(chda)2(bpp)2(H2O)2]}n 1 and {[Co(chda)(bpe)(H2O)]·3H2O}n 2 (H2chda = 1, 1-cyclohexanediacetic acid, bpp = 1, 3-bis(4-pyridinyl)propane and bpe = 1, 2-bis(4-pyridinyl)ethylene), were hydrothermally synthe-sized and then characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. Complex 1 possesses an infinite metal-organic layer based on triply bridged linear trinuclear subunits and complex 2 exhibits a square (4, 4) grid layer with dangling lateral arms resulting from eight-membered rings above and below the layer. In addition, magnetic properties of complexes 1 and 2 are also given.
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    1. [1]

      (1) Mullins, C. S.; Pecoraro, V. L. Reflections on small molecule manganese models that seek to mimic photosynthetic water oxidation chemistry. Coord. Chem. Rev. 2008, 252, 416-443.

    2. [2]

      (2) Deuss, P. J.; den Heeten, R.; Laan, W.; Kamer, P. C. J. Bioinspired catalyst design and artificial metalloenzymes. Chem. Eur. J. 2011, 17, 4680-4698.

    3. [3]

      (3) Hayashi, Y.; Santoro, S.; Azuma, Y.; Himo, F.; Ohshima, T.; Mashima, K. Enzyme-like catalysis via ternary complex mechanism: alkoxy-bridged dinuclear cobalt complex mediates chemoselective O-esterification over N-amidation, J. Am. Chem. Soc. 2013, 135, 6192-6199.

    4. [4]

      (4) Giri, S.; Biswas, S.; Drew, M. G. B.; Ghosh, A.; Saha, S. K. Structure and magnetic properties of a tetranuclear Cu(II) complex containing the 2-(pyridine-2-yliminomethyl)-phenol ligand. Inorg. Chim. Acta 2011, 368, 152-156.

    5. [5]

      (5) Stamatatos, T. C.; Boudalis, A. K.; Pringouri, K. V.; Raptopoulou, C. P.; Terzis, A.; Wolowska, J.; McInnes, E. J. L.; Perlepes, S. P. Mixed-valence cobalt(II/III) carboxylate clusters: CoII4CoIII2 and CoIICoIII2 complexes from the use of 2-(hydroxymethyl)pyridine. Eur. J. Inorg. Chem. 2007, 5098-5104.

    6. [6]

      (6) Reger, D. L.; Pascui, A. E.; Smith, M. D.; Jezierska, J.; Ozarowski, A. Dinuclear complexes containing linear M-F-M (M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)) bridges: trends in structures, antiferromagnetic superexchange interactions, and spectroscopic properties. Inorg. Chem. 2012, 51, 11820-11836.

    7. [7]

      (7) Yilmaz, V. T.; Hamamci, S.; Thöne, C. Cobalt(II) complexes of 2-methanol-, 2, 6-dimethanol- and 2-ethanolpyridines: syntheses, spectroscopic, thermal and structural characterizations of [Co2(μ-Cl)2(mpy)4]Cl2·H2O, [Co(dmpy)2]Cl2 and [Co(Cl)4](Hpyet)2 (mpy = 2-methanolpyridine; dmpy = 2, 6-dimethanolpyridine and Hpyet = 2-ethanolpyridinium). Polyhedron 2004, 23, 841-848.

    8. [8]

      (8) Laine, T. V.; Klinga, M.; Leskelä, M. Synthesis and X-ray structures of new mononuclear and dinuclear diimine complexes of late transition metals. Eur. J. Inorg. Chem. 1999, 959-964.

    9. [9]

      (9) Darling, K.; Ouellette, W.; Prosvirin, A.; Walter, S.; Dunbar, K. R.; Zubieta, J. Hydrothermal synthesis and structures of materials of the M(II)/tetrazole/sulfate family (M(II) = Co, Ni; tetrazole = 3- and 4-pyridyltetrazole and pyrazinetetrazole). Polyhedron 2013, 58, 18-29.

    10. [10]

      (10) Pleus, R. J.; Waden, H.; Saak, W.; Haase, D.; Pohl, S. Preparation of the first sulfur-containing cobalt and nickel complexes stabilized by the macrocyclic cyclam ligand; observation of S-H bond activation. J. Chem. Soc., Dalton Trans. 1999, 2601-2610.

    11. [11]

      (11) Marsh, R. E.; Thewalt, U. Structure of racemic μ-amido-μ-hydroxy-bis[bis(ethylenediamine)cobalt(III)] tetranitrate hydrate. Inorg. Chem. 1971, 10, 1789-1795.

    12. [12]

      (12) Saunders, L. N.; Pratt, M. E.; Hann, S. E.; Dawe, L. N.; Decken, A.; Kerton, F. M.; Kozak, C. M. Structural variations in the coordination chemistry of amine-bis(phenolate) cobalt(II/III) complexes. Polyhedron 2012, 46, 53-65.

    13. [13]

      (13) Sharma, A. K.; Lloret, F.; Mukherjee, R. Phenolate- and acetate (both μ2-1, 1 and μ2-1, 3 modes)-bridged linear CoII3 and CoII2MnII trimers: magnetostructural studies. Inorg. Chem. 2013, 52, 4825-4833.

    14. [14]

      (14) Ma, L. F.; Li, B.; Wang, L. Y.; Fan, Y. T. Synthesis and crystal structure of a two-dimensional cobalt complex with 5-tert-butyl isophthalic acid. Chin. J. Struct. Chem. 2010, 29, 565-569.

    15. [15]

      (15) Hu, F. L.; Zou, H. H.; Zhao, X. B.; Mi, Y.; Luo, C. L.; Wang, Y. X. Second ligands-assisted structural variation of entangled coordination polymers with polycatenated or polythreaded features. CrystEngComm. 2013, 15, 1068-1076.

    16. [16]

      (16) Cao, Y. Y.; Chen, Y. M.; Li, L.; Gao, D. D.; Liu, W.; Hu, H. L.; Li, W.; Li, Y. H. A Co16 cluster and a 1-D Mn chain complex supported by benzohydroxamic acid. Dalton Trans. 2013, 42, 10912-10918.

    17. [17]

      (17) Liu, G. Z.; Li, X. L.; Xin, L. Y.; Wang, L. Y. Two topologically new trinodal cobalt(II) metal-organic frameworks characterized as a 1D metallic oxide and a 2D → 3D penetrated porous solid. CrystEngComm. 2012, 14, 5315-5321.

    18. [18]

      (18) Li, G. L.; Liu, G. Z.; Ma, L. F.; Xin, L. Y.; Li, X. L.; Wang, L. Y. Crystallographic determination of solid-state structural transformations in a dynamic metal-organic framework, Chem. Commun. 2014, 50, 2615-2617.

    19. [19]

      (19) He, J. R.; Wang, Y. L.; Bi, W. H.; Cao, R. Syntheses, structures and fluorescence of two Cd(II) complexes constructed from 1, 1'-cyclohexanediacetic acid. Chin. J. Inorg. Chem. 2006, 22, 1380-1386.

    20. [20]

      (20) Liu, T. F.; Lü, J.; Cao, R. Coordination polymers based on flexible ditopic carboxylate or nitrogen-donor ligands. CrystEngComm. 2010, 12, 660-670.

    21. [21]

      (21) Pigge, F. C. Losing control? “Design” of crystalline organic and metal-organic networks using conformationally flexible building blocks. CrystEngComm. 2011, 13, 1733-1748.

    22. [22]

      (22) Sheldrick, G. M. A Program for the Siemens Area Detector Absorption Correction. University of Göttingen, Germany 1997.

    23. [23]

      (23) Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Gottingen, Göttingen, Germany 1997.

    24. [24]

      (24) Sheldrick, G. M. SHELXL-97, Program for Refinement of Crystal Structures. University of Gottingen, Göttingen, Germany 1997.

    25. [25]

      (25) Sun, H. L.; Wang, Z. M.; Gao, S. Synthesis, crystal structures, and magnetism of cobalt coordination polymers based on dicyanamide and pyrazine-dioxide derivatives. Inorg. Chem. 2005, 44, 2169-2176.

    26. [26]

      (26) Su, Z.; Fan, J.; Chen, M.; Okamura, T.; Sun, W. Y. Syntheses, characterization, and properties of three-dimensional pillared frameworks with entanglement. Cryst. Growth Des. 2011, 11, 1159-1169.

    27. [27]

      (27) Fisher, M. E. Magnetism in one-dimensional systems- the Heisenberg model for infinite spin. Am. J. Phys. 1964, 32, 343-346.

    28. [28]

      (28) Ma, B. Q.; Gao, S.; Yi, T.; Xu, G. X. One-dimensional coordination polymers [Co(acac)2pz]n and [Co(acac)2(4, 4'-bipy)]n (acac = acetylacetone, pz = pyrazine, bipy = 4, 4'-bipyridine): synthesis, structures and magnetic properties. Polyhedron 2001, 20, 1255-1261.

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