Citation: ZHANG Cong-Cong, ZHU Ling, FAN Cong-Bin, PU Shou-Zhi. Crystal Structure and Photoreactive Properties of 1-(2,5-Dimethyl-3-thienyl)-2-[2-methyl-5-(N-(quinolin-8-yl)-2-carboxamide)-3-thienyl)]perfluorocyclopentene[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 413-420. doi: 10.14102/j.cnki.0254-5861.2011-0856 shu

Crystal Structure and Photoreactive Properties of 1-(2,5-Dimethyl-3-thienyl)-2-[2-methyl-5-(N-(quinolin-8-yl)-2-carboxamide)-3-thienyl)]perfluorocyclopentene

1.
Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science & Technology Normal University, Nanchang 330013, China

Received Date: 7 June 2015
Available Online: 13 August 2015
Fund Project: Supported by the National Natural Science Foundation of China (51373072, 21363009) (51373072, 21363009) the Project of Natural Science Foundation of Jiangxi Province (20142BAB203005) (20142BAB203005) the Project of Science Funds of Jiangxi Education Office (KJLD12035) (KJLD12035) the Young scientisttraining program of Jiangxi (20153BCB23008) (20153BCB23008)

The photochromic title compound, C₂₆H₁₈F₆N₂OS₂, contains a 2, 5-dimethylthio-phene ring and a N-formyl aminoquinolinyl thiophene ring on the C=C double bond of the cyclopentene ring. The dihedral angles between the cyclopentene and attached N-formyl aminoquinolinyl thiophene ring and 2, 5-dimethylthiophene ring are 63.0° and 137.1°, respectively. The dihedral angle between the thiophene ring and the adjacent aminoquinoline ring is 5.7°. The molecule adopts an antiparallel conformation, with a distance between the two photoreactive C atoms of 3.763 Å. In addition, the absorption and fluorescence spectral changes were measured in acetonitile and solid at room temperature, and the result showed that the title compound could undergo photochromic reaction in both states.
- single-crystal,
- X-ray,
- diarylethene,
- photochromism
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