Citation: WANG Xiu-Yan, WANG Wei, ZHAO Fang-Wei. Crystal Structure, Thermal Behavior and Luminescence of a New Dimeric Manganese(II) Complex Constructed with 3-Carboxy-1-carboxymethyl-2-oxidopyridinium[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 392-396. doi: 10.14102/j.cnki.0254-5861.2011-0849 shu

Crystal Structure, Thermal Behavior and Luminescence of a New Dimeric Manganese(II) Complex Constructed with 3-Carboxy-1-carboxymethyl-2-oxidopyridinium

WANG Xiu-Yan ^a,b,, ,
WANG Wei ^a,b ,
ZHAO Fang-Wei ^a,b

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China;
2.
b Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: WANG Xiu-Yan,
Received Date: 15 June 2015
Available Online: 8 October 2015
Fund Project: Supported by the Institute Foundation of Siping city (No. 2013036) (No. 2013036)

A new dimeric Mn(II) complex, namely, [Mn(L)(PIP)]₂·H₂O (1), was synthesized under hydrothermal condition (H₂L = 3-carboxy-1-carboxymethyl-2-oxidopyridinium and PIP = 2-(pyridin-3-yl)-1H-imidazo[4, 5-f][1, 10]phenanthroline). It crystallizes in triclinic, space group P1 with a = 9.2037(13), b = 9.6794(13), c = 14.649(3) Å, α = 94.858(3), β = 94.928(3), γ = 114.468(2)°, V = 1172.9(3) Å³, Z = 1, C₅₂H₃₄Mn₂N₁₂O₁₁, M_r = 1112.79, D_c = 1.575 g/cm³, F(000) = 568, μ(MoKa) = 0.618 mm^-1, R = 0.0432 and wR = 0.1151. In 1, two L anions bridge two Mn(II) atoms to give a dimeric [Mn(L)(PIP)] unit with the Mn…Mn distance of 3.009(2) Å. The two PIP ligands are located on both sides of the dimer, which provides suitable π-π stacking interactions between PIP ligands. By these π-π stacking interactions, adjacent dimers are extended into a two-dimensional supramolecular layer. Further, the strong N-H…O hydrogen bond stabilizes the supramolecular layer structure of 1. Moreover, the thermal behavior and luminescent property of 1 have been studied.
- crystal structure,
- dimer,
- 3-carboxy-1-carboxymethyl-2-oxidopyridinium,
- 2-(pyridin-3-yl)-1H-imidazo[4,5-f][1,10]phenanthroline
1. [1]
  (1) Du, X.; Fan, R.; Wang, X.; Qiang, L.; Wang, P.; Gao, S.; Zhang, H.; Yang, Y.; Wang, Y. Combined effect of hydrogen bonding and π…π stacking interactions in the assembly of indium(III) metal-organic materials: structure-directing and aggregation-induced emission behavior. Cryst. Growth Des. 2015, 15, 2402-2412.
2. [2]
  (2) Zhou, J. M.; Shi, W.; Xu, N.; Cheng, P. Highly selective luminescent sensing of fluoride and organic small-molecule pollutants based on novel lanthanide metal-organic frameworks. Inorg. Chem. 2013, 52, 8082-8090.
3. [3]
  (3) Lipstman, S.; Goldberg, I. Versatile molecular recognition features of tetra(3-pyridyl)porphyrin in crystal engineering. Cryst. Growth Des. 2010, 10, 4596-4606.
4. [4]
  (4) Lin, Z. J.; Han, L. W.; Wu, D. S.; Huang, Y. B.; Cao, R. Structure versatility of coordination polymers constructed from a semirigid tetracarboxylate ligand: syntheses, structures, and photoluminescent properties. Cryst. Growth Des. 2013, 13, 255-263.
5. [5]
  (5) Wang, X. Y.; Liu, F. Y.; Zhang, Y. N.; Xu, Z. L. Synthesis, crystal structure and photoluminescence of a new Zn(II) dimer constructed by 1, 10-phenanthroline derivative and flexible dicarboxylate. Chin. J. Struct. Chem. 2014, 33, 33-36.
6. [6]
  (6) Zhang, Y. N.; Liu, P.; Wang, Y. Y.; Wu, L. Y.; Pang, L. Y.; Shi, Q. Z. Syntheses and crystal structures of a series of Zn(II)/Cd(II) coordination polymers constructed from a flexible 6, 6'-dithiodinicotinic acid. Cryst. Growth Des. 2011, 11, 1531-1541.
7. [7]
  (7) Dunne, S. J.; Surrmers, L. A.; Nagy-Felsobuki, E. I. Von. Conformational and UV photoelectron spectroscopy analysis of the chalcogenobispyridines. Coord. Chem. Rev. 1997, 165, 1-92.
8. [8]
  (8) Liu, D.; Lu, Y.; Tan, H. Q.; Wang, T. T.; Wang, E. B. Series of organic-inorganic hybrid rare earth derivatives based on [MnV₁₃O₃₈]^7- polyoxoanion: syntheses, structures, and magnetic and electrochemical properties. Cryst. Growth Des. 2015, 15, 103-114.
9. [9]
  (9) Lipstman, S.; Goldberg, I. Supramolecular crystal chemistry with porphyrin tinkertoys. Hydrogen-bonding and coordination networks with the “chair” and “table” conformers of tetra(3-carboxyphenyl)porphyrin. Cryst. Growth Des. 2013, 13, 942-952.
10. [10]
  (10) O'Keeffe, M.; Yaghi, O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. Chem. Rev. 2012, 112, 675-702.
11. [11]
  (11) Mihalcea, I.; Zill, N.; Mereacre, V.; Anson, C. E.; Powell, A. K. Spontaneous resolution in homochiral helical [Ln(nic)₂(Hnic)(NO₃)] coordination polymers constructed from a rigid non-chiral organic ligand. Cryst. Growth Des. 2014, 14, 4729-4734.
12. [12]
  (12) Hu, B. W.; Zhao, J. P.; Tao, J.; Sun, X. J.; Yang, Q.; Zhang, X. F.; Bu, X. H. A new azido-nickel compound with three-dimensional kagomé topology. Cryst. Growth Des. 2010, 10, 2829-2831.
13. [13]
  (13) Wang, X. Y.; Liu, R.; Li, F. Y.; Meng, X. Y.; Sun, Q. H.; Zhao, Z. Y. Crystal structure and luminescence of a new Zn(II) complex [Zn(L)(IPP)(H₂O)]·2H₂O based on nicotinate derivative and 1, 10-phenanthroline derivative. Chin. J. Struct. Chem. 2015, 34, 960-964.
14. [14]
  (14) Sheldrick, G. M. SHELXS-97, Program for Solution of Crystal Structures. University of Göttingen, Germany 1997.
15. [15]
  (15) Sheldrick, G. M. SHELXL-97, Program for Refinement of Crystal Structures. University of Göttingen, Germany 1997.
16. [16]
  (16) Zang, S. Q.; Fan, Y. J.; Li, J. B.; Hou, H. W.; Mak, T. C. W. Halogen bonding in the assembly of coordination polymers based on 5-iodo-isophthalic acid. Cryst. Growth Des. 2011, 11, 3395-3405.
17. [17]
  (17) Wang, X. Y.; Zhao, Z. Y.; Liu, R.; Xu, Y.; Li, X. H.; Xu, Z. L. Synthesis, crystal structure and luminescence of a new Zn(II) complex [Zn(1, 2, 3-HBTC)(L)]₂ constructed by mixed ligands. Chin. J. Struct. Chem. 2015, 34, 725-728.
1. [1]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
2. [2]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
3. [3]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
4. [4]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
9. [9]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
12. [12]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
13. [13]
  Peiyan Zhu , Yanyan Yang , Hui Li , Jinhua Wang , Shiqing Li . Rh(Ⅲ)‐Catalyzed sequential ring‐retentive/‐opening [4 + 2] annulations of 2H‐imidazoles towards full‐color emissive imidazo[5,1‐a]isoquinolinium salts and AIE‐active non‐symmetric 1,1′‐biisoquinolines. Chinese Chemical Letters, 2024, 35(10): 109533-. doi: 10.1016/j.cclet.2024.109533
14. [14]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
15. [15]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
16. [16]
  Bairu Meng , Zongji Zhuo , Han Yu , Sining Tao , Zixuan Chen , Erik De Clercq , Christophe Pannecouque , Dongwei Kang , Peng Zhan , Xinyong Liu . Design, synthesis, and biological evaluation of benzo[4,5]thieno[2,3-d]pyrimidine derivatives as novel HIV-1 NNRTIs. Chinese Chemical Letters, 2024, 35(6): 108827-. doi: 10.1016/j.cclet.2023.108827
17. [17]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
18. [18]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
19. [19]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
20. [20]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(834)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142