Citation: WANG Xiu-Yan, WANG Wei, ZHAO Fang-Wei. Crystal Structure, Thermal Behavior and Luminescence of a New Dimeric Manganese(II) Complex Constructed with 3-Carboxy-1-carboxymethyl-2-oxidopyridinium[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 392-396. doi: 10.14102/j.cnki.0254-5861.2011-0849 shu

Crystal Structure, Thermal Behavior and Luminescence of a New Dimeric Manganese(II) Complex Constructed with 3-Carboxy-1-carboxymethyl-2-oxidopyridinium

WANG Xiu-Yan ^a,b,, ,
WANG Wei ^a,b ,
ZHAO Fang-Wei ^a,b

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China;
2.
b Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: WANG Xiu-Yan,
Received Date: 15 June 2015
Available Online: 8 October 2015
Fund Project: Supported by the Institute Foundation of Siping city (No. 2013036) (No. 2013036)

A new dimeric Mn(II) complex, namely, [Mn(L)(PIP)]₂·H₂O (1), was synthesized under hydrothermal condition (H₂L = 3-carboxy-1-carboxymethyl-2-oxidopyridinium and PIP = 2-(pyridin-3-yl)-1H-imidazo[4, 5-f][1, 10]phenanthroline). It crystallizes in triclinic, space group P1 with a = 9.2037(13), b = 9.6794(13), c = 14.649(3) Å, α = 94.858(3), β = 94.928(3), γ = 114.468(2)°, V = 1172.9(3) Å³, Z = 1, C₅₂H₃₄Mn₂N₁₂O₁₁, M_r = 1112.79, D_c = 1.575 g/cm³, F(000) = 568, μ(MoKa) = 0.618 mm^-1, R = 0.0432 and wR = 0.1151. In 1, two L anions bridge two Mn(II) atoms to give a dimeric [Mn(L)(PIP)] unit with the Mn…Mn distance of 3.009(2) Å. The two PIP ligands are located on both sides of the dimer, which provides suitable π-π stacking interactions between PIP ligands. By these π-π stacking interactions, adjacent dimers are extended into a two-dimensional supramolecular layer. Further, the strong N-H…O hydrogen bond stabilizes the supramolecular layer structure of 1. Moreover, the thermal behavior and luminescent property of 1 have been studied.
- crystal structure,
- dimer,
- 3-carboxy-1-carboxymethyl-2-oxidopyridinium,
- 2-(pyridin-3-yl)-1H-imidazo[4,5-f][1,10]phenanthroline
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