Citation: XUE Li-Ping, SHAN Li-Li, FENG Wen-Jing. Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 293-297. doi: 10.14102/j.cnki.0254-5861.2011-0845 shu

Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: XUE Li-Ping,
Received Date: 15 June 2015
Available Online: 6 September 2015
Fund Project: This work was supported by the Natural Science Foundation of China (21401097) for the financial support. (21401097)

A new cadmium(II) coordination polymer, [Cd(Hcna)₂]_n (1), was hydrothermally synthesized based on 5-(4-carboxyphenoxy)nicotinic acid (H₂cna) organic linker. X-ray single- crystal diffraction determination reveals that 1 crystallizes in the monoclinic P2₁/c space group, with a = 10.101(2), b = 7.9139(17), c = 15.627(3) Å, β = 103.364(3)°, V = 1215.4(4) Å³, Z = 2, M_r = 628.81, D_c= 1.718 Mg/m³, μ = 0.963 mm^-1, F(000) = 628, the final R = 0.0177 and wR = 0.0432 for 2263 observed reflections with I > 2σ(I). In 1, the Cd(II) cations are connected by nicotiniate units to form a two-dimensional (2D) layer, and it is further linked through benzoate units to form a three-dimensional (3D) structure. Topologically, the structure of 1 represents a 3,6-connected 3D rtl topology. Furthermore, thermal stability and photoluminescent property of 1 have also been investigated.
- cadmium coordination polymer,
- crystal structure,
- 5-(4-carboxyphenoxy)nicotinic acid,
- rtl topology,
- luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142