Citation: SHENG Dong-Hai, DAN Wen-Yan, LUO Gen-Xiang, DENG Ming-Li. A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO₂ Adsorption and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 264-270. doi: 10.14102/j.cnki.0254-5861.2011-0838 shu

A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO₂ Adsorption and Luminescent Property

1.
a College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China;
2.
b Department of Chemistry, Fudan University, Shanghai 200433, China

Corresponding author: DENG Ming-Li,
Received Date: 5 June 2015
Available Online: 30 September 2015
Fund Project: The project was supported by the NNSFC (No. 21203032) (No. 21203032)

A three-dimensional coordination polymer, namely {[Zn₂(tzba)(dmtrz)(OH)]·3H₂O}_n (1, H₂tzba = 4-(5H-tetrazol)benzoic acid, Hdmtrz = 3,5-dimethyl-1H,1,2,4-triazole), was hydro- thermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic system, P2₁/c space group with a = 8.018(11), b = 21.04(3), c = 11.069(14) Å, β = 91.26(3)°, V = 1867(4) Å³, Z = 4, D_c = 1.729 g/cm³, F(000) = 984, μ = 2.614 mm^-1, R(F² > 2σ(F²)) = 0.0612 and wR(F²) = 0.1533. Topological analysis reveals that compound 1 is a (3,5)-connected structure with a Schläfli symbol of (4².6)(4².6⁵.8³), which is a rarely observed lhh topology. In addition, the CO₂ adsorption performance and luminescent property of 1 have also been studied.
- crystal structure,
- mixed ligands,
- topology
1. [1]
  (1) Zhang, J. P.; Liao, P. Q.; Zhou, H. L.; Lin, R. B.; Chen, X. M. Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers, Chem. Soc. Rev. 2014, 43, 5789-5814.
2. [2]
  (2) Suh, M. P.; Park, H. J.; Prasad, T. K.; Lim, D. W. Hydrogen storage in metal-organic frameworks. Chem. Rev. 2012, 112, 782-835.
3. [3]
  (3) Zhao, M.; Ou, S.; Wu, C. D. Porous metal-organic frameworks for heterogeneous biomimetic catalysis. Acc. Chem. Res. 2014, 47, 1199-1207.
4. [4]
  (4) Li, D. S.; Zhao, J.; Wu, Y. P.; Liu, B.; Bai, L.; Zou, K.; Du, M. Co-5/Co-8-cluster-based coordination polymers showing high-connected self-penetrating networks: syntheses, crystal structures, and magnetic properties. Inorg. Chem. 2013, 52, 8091-8098.
5. [5]
  (5) Hu, Z. C.; Deibert, B. J.; Li, J. Luminescent metal-organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 2014, 43, 5815-5840.
6. [6]
  (6) Li, M.; Ni, W. X.; Zhan, S. Z.; Zhou, X.; Li, D. Supramolecular coordination compounds and their crystalline aggregates: syntheses, structures and functions. Chinese Science Bulletin 2014, 59, 1382-1397.
7. [7]
  (7) Zhang, Y. B.; Zhang, J. P. Porous coordination polymers constructed from anisotropic metal-carboxylate-pyridyl clusters. Pure Appl. Chem. 2013, 85, 405-416.
8. [8]
  (8) Haldara, R.; Maji, T. K. Metal-organic frameworks based on mixed linker systems: structural diversities towards functional materials. CrystEngComm. 2013, 15, 9276-9295.
9. [9]
  (9) Chevreau, H.; Devic, T.; Salles, F.; Maurin, G.; Stock, N.; Serre, C. Mixed-linker hybrid superpolyhedra for the production of a series of large-pore iron(III) carboxylate metal-organic frameworks. Angew. Chem. Int. Ed. 2013, 52, 5056-5060.
10. [10]
  (10) Du, M.; Li, C. P.; Liu, C. S.; Fang, S. M. Design and construction of coordination polymers with mixed-ligand synthetic strategy. Coord. Chem. Rev. 2013, 257, 1282-1305.
11. [11]
  (11) Lei, H.; Yan, Y. L.; Chen, X. M. Porous metal-organic framework based on μ4-oxo tetrazinc clusters: sorption and guest-dependent luminescent properties. Inorg. Chem. 2008, 47, 1346-1351.
12. [12]
  (12) Lin, R. B.; Li, F.; Liu, S. Y.; Qi, X. L.; Zhang, J. P.; Chen, X. M. A noble-metal-free porous coordination framework with exceptional sensing efficiency for oxygen. Angew. Chem. Int. Ed. 2013, 52, 13429 -13433.
13. [13]
  (13) Zheng, Q. S.; Yang, F. L.; Deng, M. L.; Ling, Y.; Liu, X. F.; Chen, Z. X.; Wang, Y. H.; Weng L. H.; Zhou Y. M. A porous metal-organic framework constructed from carboxylate-pyrazolate shared heptanuclear zinc clusters: synthesis, gas adsorption, and guest-dependent luminescent properties. Inorg. Chem. 2013, 52, 10368-10374.
14. [14]
  (14) Montoro, C.; Linares, F.; Procopio, E. Q.; Senkovska, I.; Kaskel, S.; Galli, S.; Masciocchi, N.; Barea, E.; Navarro, J. A. R. Capture of nerve agents and mustard gas analogues by hydrophobic robust MOF-5 type metal-organic frameworks. J. Am. Chem. Soc. 2011, 133, 11888-11891.
15. [15]
  (15) Tu, B. B.; Pang, Q. Q.; Wu, D. F.; Song, Y. N.; Weng, L. H.; Li, Q. W. Ordered vacancies and their chemistry in metal-organic frameworks. J. Am. Chem. Soc. 2014, 136, 14465-14471.
16. [16]
  (16) Ling, Y.; Chen, Z. X.; Zhai, F. P.; Zhou, Y. M.; Weng, L. H.; Zhao, D. Y. A zinc(II) metal-organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers. Chem. Commun. 2011, 47, 7197-7199.
17. [17]
  (17) Ling, Y.; Yang, F. L.; Deng, M. L.; Chen, Z. X.; Liu, X. F.; Weng, L. H.; Zhou, Y. M. Novel iso-reticular Zn(II) metal-organic frameworks constructed by trinuclear-triangular and paddle-wheel units: synthesis, structure and gas adsorption. Dalton Trans. 2012, 41, 4007-2010.
18. [18]
  (18) Yang, F. L.; Zheng, Q. S.; Chen, Z. X.; Yun, L.; Liu, X. F.; Weng, L. H.; Zhou, Y. M. A three-dimensional structure built of paddle-wheel and triazolate-dinuclearmetal clusters: synthesis, deformation and reformation of paddle-wheel unit in the single-crystal-to-single-crystal transformation. CrystEngComm. 2013, 15, 7031-7037.
19. [19]
  (19) Deng, M. L.; Yang, P.; Liu, X. F.; Xia, B.; Chen, Z. X.; Ling, Y.; Weng, L. H.; Zhou, Y. M.; Sun, J. Y. End-end connection pattern of trinuclear-triangular copper cluster for construction of two metal-organic frameworks: syntheses, structures, magnetic and gas adsorption properties. Cryst. Growth Des. 2015, 15, 1526-1534.
20. [20]
  (20) Tu, B.; Pang, Q.; Ning, E.; Yan, W.; Qi, Y.; Wu, D.; Li, Q. Heterogeneity within a mesoporous metal-organic framework with three distinct metal-containing building units. J. Am. Chem. Soc. DOI: 10.1021/jacs.5b07687.
21. [21]
  (21) Du, M.; Li, C. P.; Chen, M.; Ge, Z. W.; Wang, X.; Wang, L.; Liu, C. S. Divergent kinetic and thermodynamic hydration of a porous Cu(II) coordination polymer with exclusive CO₂ sorption selectivity. J. Am. Chem. Soc. 2014, 136, 10906-10909.
22. [22]
  (22) Song, W. C.; Li, J. R.; Song, P. C.; Tao, Y.; Yu, Q.; Tong, X. L.; Bu, X. H. Tuning the framework topologies of CoII-doped ZnII-tetrazole-benzoate coordination polymers by ligand modifications: structures and spectral studies. Inorg. Chem. 2009, 48, 3792-3799.
23. [23]
  (23) Ouellette, W.; Liu, H. X.; Whitenack, K. O.; Connor, C. J.; Zubieta, J. A three-dimensional porous and magnetic framework constructed from {Cu₄(μ₄-Cl)}^{+7 c}lusters and 4-(1H-tetrazol-5yl)-benzoic acid, (Me₂NH₂)[Cu₄Cl(tba)₄(H₂O)₄]·2DMF. Cryst. Growth Des. 2009, 9, 4258-4261.
24. [24]
  (24) Yao, R. X.; Qin, Y. L.; Ji, F.; Zhao, Y. F.; Zhang, X. M. Triangle, square and delta-chain based cobalt tetrazolate magnets. Dalton Trans. 2013, 42, 6611-6618.
25. [25]
  (25) Hou, L.; Zhang, J. P.; Chen, X. M. Two metal-carboxylate frameworks featuring uncommon 2D + 3D and 3-fold-interpenetration: (3,5)-connected isomeric hms and gra nets. Cryst. Growth Des. 2009, 9, 2415-2419.
26. [26]
  (26) Wei, Q.; Yang, D. L.; Larson, T. E.; Kinnibrugh, T. L.; Zou, R. Q.; Henson, N. J.; Timofeeva, T.; Xu, H. W.; Zhao, Y. S.; Mattes, B. R. Kinetic hysteresis in gas adsorption behavior for a rigid MOF arising from zig-zag channel structures. J. Mater. Chem. 2012, 22, 10166-10171.
27. [27]
  (27) Zhang, J. P.; Zhang, Y. B.; Lin, B. J.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2012, 112, 1001-1033.
28. [28]
  (28) Macleod, I. T.; Tiekink, E. R.T.; Young, C. G. Carbonyl-molybdenum complexes of the hydrotris(3,5-dimethyl-1,2,4-triazol-1-yl)borate ligand. J. Organomet. Chem. 1996, 506, 301-306.
29. [29]
  (29) Bruker, S. Program for empirical absorption correction of area detector data. Bruker AXS 1999.
30. [30]
  (30) Sheldrick, G. M. A short history of SHELX. Acta Cryst. A 2008, 64, 112-122.
31. [31]
  (31) Düren, T.; Millange, F.; Férey, G.; Walton, K. S.; Snurr, R. Q. Calculating geometric surface areas as a characterization tool for metal-organic frameworks. J. Phys. Chem. C. 2007, 111, 15350-15356.
32. [32]
  (32) Li, H. H.; Shi, W.; Zhao, K. N.; Niu, Z.; Chen, X. T.; Cheng, P. A robust porous metal-organic framework with a new topology that demonstrates pronounced porosity and high-efficiency sorption/selectivity properties of small molecules. Chem. Eur. J. 2012, 18, 5715-5723.
33. [33]
  (33) Wang, H.; Yi, F. Y.; Dang, S.; Tian, W. G.; Sun, Z. M. Rational assembly of Co/Cd-MOFs featuring topological variation. Cryst. Growth Des. 2014, 14, 147-156.
34. [34]
  (34) Chen, D. M.; Zhang, X. P.; Shi, W.; Cheng, P. Tuning two-dimensional layer to three-dimensional pillar-layered metal-organic frameworks: polycatenation and interpenetration behaviors. Cryst. Growth Des. 2014, 14, 6261-6268.
35. [35]
  (35) Zheng, X. F.; Zhou, L.; Huang, Y. M.; Wang, C. G.; Duan, J. G.; Wen, L. L.; Tian, Z. F.; Li, D. F. A series of metal-organic frameworks based on 5-(4-pyridyl)-isophthalic acid: selective sorption and fluorescence sensing. J. Mater. Chem. A 2014, 2, 12413-12422.
36. [36]
  (36) Park, J.; Li, J. R.; Chen Y. P.; Yu, J. M.; Yakovenko, A. A. Z.; Wang, Z. Y. U.; Sun, L. B.; Balbuenab, P. B.; Zhou, H. C. A versatile metal-organic framework for carbon dioxide capture and cooperative catalysis. Chem. Commun. 2012, 48, 9995-9997.
37. [37]
  (37) Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald T. M.; Bloch, E. D.; Herm, Z. R.; Bae, T. H.; Long, J. R. Carbon dioxide capture in metal-organic frameworks. Chem. Rev. 2012, 112, 724-781.
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO2 Adsorption and Luminescent Property

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通讯作者: 陈斌, bchen63@163.com

A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO₂ Adsorption and Luminescent Property