Citation: ZHANG Tian, TIAN Ai-Qin, FENG Xun, Seik Weng Ng, TIAN Pan-Hao, WANG Yang. Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 279-285. doi: 10.14102/j.cnki.0254-5861.2011-0836 shu

Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid

ZHANG Tian ^a ,
TIAN Ai-Qin ^b ,
FENG Xun ^a,, ,
Seik Weng Ng ^c,d ,
TIAN Pan-Hao ^a ,
WANG Yang ^a

1.
a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China;
2.
b Basic Courses Education Department, Henan Forestry Vocational College, Luoyang 471002, China;
3.
c Department of Chemistry, University of Malaya, Kuala Lumpur 50603, Malaysia;
4.
d Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 80203, Saudi Arabia

Corresponding author: FENG Xun,
Received Date: 5 June 2015
Available Online: 19 August 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21273101) (No. 21273101) Program for Science & (No. 142102310483)

A new cadmium(II) complex [Cd(Hminic)(IP)]_n (1, Hminic = 2-hydroxy-6-methyli- sonicotinic acid, IP = imidazo[4,5-f]-1,10-phenanthroline), has been synthesized by the reaction of a Hminic and auxiliary N-containing ligands with Cd(II) ion under hydrothermal conditions. The complex was studied by elemental analysis, IR spectroscopy and X-ray crystallography. It is formulated as C₂₀H₁₃CdN₅O₃, crystallizes in monoclinic system, space group C2/c with α = 9.6764(8), b = 26.767(2), c = 14.1332(11) Å and b = 97.4510(10)°. V = 3629.7(5) Å³, Z = 8, M_r = 483.75, D_c = 1.770 g/cm³, F(000) = 1484 and µ = 1.237 mm^-1. The final refinement gave R = 0.0309 and wR = 0.0703 for 4151 reflections with I > 2s(I). In the structure of 1, two Cd(II)atoms are joined by a pair of μ₂-hydroxyl oxygen atoms giving rise to a dinuclear Cd(II) unit which is bridged by Hminic linkers to form a 1D ladder-like polymer chain. The chelating ligand IP coordinated to the Cd(II)atom, and alternately attached to both sides of the ladder-like polymer chain. Adjacent chains are further bound together by strong intermolecular hydrogen bonds and face-to-face π…π interactions, resulting in the formation of a 3D supramolecular architecture. Furthermore, the thermal stability and luminescent properties of this complex and the free ligands have been investigated.
- luminescent property,
- 2-hydroxy-6-methylisonicotinic acid,
- cadmium(II) complex
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