Citation: ZHANG Tian, TIAN Ai-Qin, FENG Xun, Seik Weng Ng, TIAN Pan-Hao, WANG Yang. Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 279-285. doi: 10.14102/j.cnki.0254-5861.2011-0836 shu

Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid

  • Corresponding author: FENG Xun, 
  • Received Date: 5 June 2015
    Available Online: 19 August 2015

    Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21273101) (No. 21273101) Program for Science & (No. 142102310483)

  • A new cadmium(II) complex [Cd(Hminic)(IP)]n (1, Hminic = 2-hydroxy-6-methyli- sonicotinic acid, IP = imidazo[4,5-f]-1,10-phenanthroline), has been synthesized by the reaction of a Hminic and auxiliary N-containing ligands with Cd(II) ion under hydrothermal conditions. The complex was studied by elemental analysis, IR spectroscopy and X-ray crystallography. It is formulated as C20H13CdN5O3, crystallizes in monoclinic system, space group C2/c with α = 9.6764(8), b = 26.767(2), c = 14.1332(11) Å and b = 97.4510(10)°. V = 3629.7(5) Å3, Z = 8, Mr = 483.75, Dc = 1.770 g/cm3, F(000) = 1484 and µ = 1.237 mm-1. The final refinement gave R = 0.0309 and wR = 0.0703 for 4151 reflections with I > 2s(I). In the structure of 1, two Cd(II) atoms are joined by a pair of μ2-hydroxyl oxygen atoms giving rise to a dinuclear Cd(II) unit which is bridged by Hminic linkers to form a 1D ladder-like polymer chain. The chelating ligand IP coordinated to the Cd(II) atom, and alternately attached to both sides of the ladder-like polymer chain. Adjacent chains are further bound together by strong intermolecular hydrogen bonds and face-to-face π…π interactions, resulting in the formation of a 3D supramolecular architecture. Furthermore, the thermal stability and luminescent properties of this complex and the free ligands have been investigated.
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    1. [1]

      (1) Yaghi, O. M.; O′Keefe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J. Reticular synthesis and the design of new materials. Nature 2003, 423, 705-714.

    2. [2]

      (2) O′Keeffe, M.; Yaghi, O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. Chem. Rev. 2012, 112, 675-702.

    3. [3]

      (3) Chen, B.; Xiang, S.; Qian, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115-1124.

    4. [4]

      (4) Zhao, Y.; Deng, D. S.; Ma, L. F.; Ji, B. M.; Wang, L. Y. A new copper-based metal-organic framework as a promising heterogeneous catalyst for chemo- and regio-selective enamination of b-ketoesters. Chem. Commun. 2013, 49, 10299-10301.

    5. [5]

      (5) Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2011, 112, 1001-1033.

    6. [6]

      (6) Pan, M.; Su, C. Y. Coordination assembly of Borromean structures. CrystEngComm. 2014, 16, 7847-7859.

    7. [7]

      (7) Ismayilov, R. H.; Wang, W. Z.; Lee, G. H.; Yeh, C. Y.; Hua, S. A.; Song, Y.; Rohmer, M. M.; Bénard, M.; Peng, S. M. Two linear undecanickel mixed-valence complexes: increasing the size and the scope of the electronic properties of nickel metal strings. Angew. Chem. Int. Ed. 2011, 50, 2045-2048.

    8. [8]

      (8) Feng, X.; Liu, J.; Guo, J. Z.; Wang, L. Y.; Ng, S. W. A unique manganese (II) 2D polymer containing 2, 5-di(2',4'-dicarboxylphenyl) pyridine and oxalate mixed ligands:Structure and magnetic property, Inorg. Chem. Commun. 2014, 50, 42-47.

    9. [9]

      (9) Li, C. P.; Du, M. Role of solvents in coordination supramolecular systems. Chem. Commun. 2011, 47, 5958-5972.

    10. [10]

      (10) Erxleben, A. Structures and properties of Zn(II) coordination polymers. Coord. Chem. Rev. 2003, 246, 203-228.

    11. [11]

      (11) Teo, P.; Hor, T. S. A. Spacer directed metallo-supramolecular assemblies of pyridine carboxylates. Coord. Chem. Rev. 2011, 255, 273-289.

    12. [12]

      (12) Boča, M.; Jameson, R. F.; Linert, W. Fascinating variability in the chemistry and properties of 2, 6-bis-(benzimidazol-2-yl)-pyridine and 2,6-bis-(benzthiazol-2-yl)-pyridine and their complexes. Coord. Chem. Rev. 2011, 255, 290-317.

    13. [13]

      (13) Mal, D.; Sen, R.; Brandão, P.; Lin, Z. Control formation of rigid linear and flexible zig-zig complexes based on Zn(II) and hydroxyquinoline carboxylate ligand system. Inorg. Chem. Commun. 2013, 30, 111-114.

    14. [14]

      (14) Yuan, G.; Shao, K. Z.; Hao, X. R.; Pan, Y. R.; Su, Z. M. Synthesis, structure, and photoluminescent property of a trinuclear CdII complex based on semi-rigid bis(imidazole-4,5-dicarboxylate) ligand. Inorg. Chem. Commun. 2014, 42, 15-19.

    15. [15]

      (15) Sheldrick, G. M. SHELXS97, Program for the Solution of Crystal Structure. University of Göttingen, Germany 1997.

    16. [16]

      (16) Sheldrick, G. M. SHELXL97. Program for the Crystal Structure Refinement. University of Göttingen, Germany 1997.

    17. [17]

      (17) Du, M.; Jiang, X. J.; Zhao, X. J. Molecular tectonics of mixed-ligand metal-organic frameworks (MOFs): positional isomeric effect, metal-directed assembly and structural diversification. Inorg. Chem. 2007, 46, 3984-3995.

    18. [18]

      (18) Desiraju, G. R.; Steiner, T. The Weak Hydrogen Bond in Structural Chemistry and Biology. Oxford University Press: Oxford 1999.

    19. [19]

      (19) Sun, D.; Zhang, N.; Huang, R. B.; Zheng, L. S. Series of Ag(I) coordination complexes derived from aminopyrimidyl ligands and dicarboxylates: syntheses, crystal structures, and properties. Cryst. Growth Des. 2010, 10, 3699-3709.

    20. [20]

      (20) Feng, X.; Feng, Y. Q.; Chen, J. L.; Ng, S. W.; Wang, L. Y. Reticular three-dimensional 3d-4f frameworks constructed through substituted imidazole-dicarboxylate: syntheses, luminescence and magnetic properties study, Dalton Trans. 2015, 44, 804-816.

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