Citation: LI Jie, XI Teng, YAN Biao, YANG Ming-Yan, MA Hai-Xia, SONG Ji-Rong. Crystal Structure and Antifungal Activities of a New Zn(Ⅱ) Complex Based on Triadimenol[J]. Chinese Journal of Structural Chemistry, ;2015, 34(12): 1825-1829. doi: 10.14102/j.cnki.0254-5861.2011-0825 shu

Crystal Structure and Antifungal Activities of a New Zn(Ⅱ) Complex Based on Triadimenol

LI Jie ^a ,
XI Teng ^a ,
YAN Biao ^a,b ,
YANG Ming-Yan ^c ,
MA Hai-Xia ^a ,
SONG Ji-Rong ^a,d

a.
a. School of Chemical Engineering, Northwest University/Shaanxi Key Laboratory of Physico-inorganic Chemistry, Xi'an, Shaanxi 710069, China;
b.
b. School of Chemistry and Chemical Engineering University of Yulin, Yulin, Shaanxi 719000, China;
c.
c. School of Environmental Science and Engineering, Chang'an University, Xi'an, Shaanxi 710054, China;
d.
d. Conservation Technology Department, the Palace Museum, Beijing 100009, China

Received Date: 26 May 2015
Available Online: 6 September 2015
Fund Project: Supported by the National Natural Science Foundation (21373161) (21373161)New Century Excellent Talents in University of Ministry of Education of China (NCET-12-1047) (NCET-12-1047)

A new Zn(Ⅱ) complex, [ZnL₂Br₂] (L=triadimenol) was synthesized by the reaction of ZnBr2 with the commercial fungicide of triadimenol, then characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The crystal structure shows that the complex [ZnL₂Br₂] crystallizes in orthorhombic, Pnam space group with a=11.263(2), b=8.4478(15), c=36.125(7) Ǻ, V=3437.2(11) Ǻ³, Z=4, C₂₈H₃₆Br₂Cl₂N₆O₄Zn, M_r=816.72, D_c=1.578 g/cm³, F(000)=1648, μ=3.236 mm^-1, the final R=0.0388 and wR=0.0879 for 2399 observed reflections with I>2σ(I). The central metals adopt square plane coordination geometry. And intermolecular hydrogen bonds connect Zn(Ⅱ) into a one-dimensional chain. In addition, the title complex and triadimenol were screened for antifungal activities against four selected fungi using the mycelial growth rate method. The results indicate that the complex synthesized shows better antifungal activities than the ligand triadimenol.
- triadimenol,
- Zn(Ⅱ) complex,
- crystal structure,
- antifungal activities
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