Citation: LU Jiu-Fu, SHI Juan, ZHENG Nan, GUO Xiao-Hua, GE Hong-Guang. Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 319-325. doi: 10.14102/j.cnki.0254-5861.2011-0814 shu

Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework

1.
Chemical Engineering College, Shaanxi University of Technology, Hanzhong 723001, China

Received Date: 19 May 2015
Available Online: 20 July 2015
Fund Project: This project was supported by the National Natural Science Foundation of China (No. 21373132) (No. 21373132)the Foundation of Shaanxi university of technology (No. SLGKY15-36) (No. SLGKY15-36)

A new coordination polymer, {[Ag₂(bpp)₂(H₂O)₂]·bpdc·3H₂O}_n, derived from the ligand biphenyl-4,4'-dicarboxylic acid (H₂bpdc), has been obtained through a hydrothermal technique (bpp = 1,3-bis(4-pyridyl)propane). Its single-crystal structure has been characterized by single-crystal X-ray diffraction, powder XRD, FT-IR, TGA and elemental analysis techniques. The single-crystal X-ray diffraction reveals that complex 1 consists of 1D infinite [Ag(bpp)(H₂O)]_nⁿ⁺ cationic chains, 2D anionic layer constructed by bpdc anions and free water which provide charge compensation in the crystal structure. The 1D infinite [Ag(bpp)(H₂O)]_nⁿ⁺cationic chains and 2D anionic layer are further stacked in -ABAB- fashion through intermolecular H-bonding to form a 3D sandwich-like framework. In addition, the luminescent property of complex 1 in the solid state at room temperature was investigated.
- Ag(Ⅰ) coordination polymer,
- crystal structure,
- luminescent property
1. [1]
  (1) Wang, C. C.; Ma, H. W. Crystal structure of catena-bis((1,3-bis(4-pyridyl)propane)-silver(I))benzene-1,4-dicarboxylate octahydrate, [{Ag(C₁₃H₁₄N₂)}₂][C₈H₄O₄]₈H₂O. N.C. S. 2007, 222, 101-105.
2. [2]
  (2) Lu, J. F.; Min, S. T.; Ge, H. G. Synthesis, crystal structures and properties of two-dimensional complexes constructed by dicarboxylate and bis(imidazole) co-ligands. J. Chem. Res. 2014, 11, 726-730.
3. [3]
  (3) Lu, J. F.; Qiao, L. J.; Li, L. Q.; Liu, Z. H. Syntheses, structures and luminescent properties of four novel Cd/Zn(II) complexes constructed from dicarboxylate and bis(imidazole) co-ligands. J. Mol. Struct. 2015, 1081, 79-84.
4. [4]
  (4) Lu, J. F.; Liu, J.; Jiang, M.; Ge, H. G. Synthesis, structure and luminescent property of a 2D Cd(II) coordination polymer based on mixed-ligands of 1,3-bis(imidazol)propane and pyridine-3,5-dicarboxylic acid. Chin. J. Struct. Chem. 2015, 2, 248-252.
5. [5]
  (5) Wang, C. C.; Wang, P. Hydrogen bonding and water networks in a 3-D coordination polymer [Ag(bpp)]₂(BDC)·8H₂O (bpp = 1,3-bis(4-pyridyl)propane; BDC = benzene-1,4-dicarboxylic acid). Asian J. Chem. 2011, 23, 1449-1452.
6. [6]
  (6) Luo, G. G.; Wu, D. L.; Wu, J. H.; Xia, J. X.; Liu, L.; Dai, J. C. Direct observation of conformational change of adipate dianions encapsulated in water clusters. CrystEngComm. 2012, 14, 5377-5380.
7. [7]
  (7) Fu, Z. Y.; Hu, S. M.; Du, W. X.; Zhang, J. J.; Xiang, S. C.; Wu, X. T. Syntheses and structures of two new coordination polymers: [Cu(C₁₄H₉O₄)(C₁₄H₁₀O₄)(C₁₂H₁₂N₂)₂] and [Ag(C₁₄H₉O₄)(C₁₃H₁₄N₂)]·0.5H₂O. Chin. J. Struct. Chem. 2004, 23, 176-182.
8. [8]
  (8) Luo, G. G.; Xiong, H. B.; Fu, Z. Y.; Dai, J. C. Observation of the novel ""three-pointed star"" cage-like (H₂O)₅ cluster in a polymeric solid {[Ag₂(bpp)₂(H₂O)₂](chd)·9H₂O}_n. Sci. Chi. Chem. 2012, 55, 2104-2114.
9. [9]
  (9) Luo, G. G.; Xiong, H. B.; Sun, D.; Wu, D. L.; Huang, R. B.; Dai, J. C. A discrete spirocyclic (H₂O)₉ cluster and 1D novel water chain with tetrameric and octameric clusters in cationic hosts. Cryst. Growth Des. 2011, 11, 1948-1956.
10. [10]
  (10) Luo, G. G.; Wu, D. L.; Li, L.; Wu, S. H.; Li, D. X.; Xiao, Z. J.; Dai, J. C. A novel 1D T5(0)A(2) water tape incorporated in the channel of the first 3D silver-suberate framework. J. Mol. Struct. 2012, 1014, 92-96.
11. [11]
  (11) Zhao, Q. H.; Chen, J.; Zhu, R. M.; Li, M. Z.; Dai, J. C.; Luo, G. G. Acyclic water tetramer and discrete (H₂O)₂₈ cluster with a novel topknot-shaped (H₂O)₂₄ cluster coexist in the voids of a Ag(I) polymeric solid. Inorg. Chem. Comm. 2012, 22, 182-186.
12. [12]
  (12) He, W. J.; Luo, G. G.; Wu, D. L.; Liu, L.; Xia, J. X.; Li, D. X.; Dai, J. C.; Xiao, Z. J. An odd-numbered heptameric water cluster containing a puckered pentamer self-assembled in a Ag(I) polymeric solid. Inorg. Chem. Comm. 2012, 18, 4-7.
13. [13]
  (13) Luo, G. G.; Li, D. X.; Wu, D. L.; Liu, L.; Zhao, Q. H.; Peng, C.; Xiao, Z. J.; Dai, J. C. Characterization of a well-resolved acyclic methanol(water)₅ heterohexamer in the solid state. Inorg. Chem. Comm. 2012, 17, 108-112.
14. [14]
  (14) Luo, G. G.; Zhu, R. M.; He, W. J.; Li, M. Z.; Zhao, Q. H.; Li, D. X.; Dai, J. C. Coexistence of cyclic (CH₃OH)₂(H₂O)₈ heterodecamer and acyclic water trimer in the channels of silver-azelate framework. J. Mol. Struct. 2012, 1021, 84-88.
15. [15]
  (15) Lu, J. F.; Ge, H. G.; Min, S. T. Syntheses and structural characterization of silver(I) complexes with pyridine and carboxylate derivatives. Rus. J. Coord Chem. 2011, 37, 37-40.
16. [16]
  (16) Sheldrick, G. M. SADABS, A Program for Empirical Absorption Correction of Area detector Data. University of Göttingen, Germany 1997.
17. [17]
  (17) Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997.
18. [18]
  (18) Sheldrick, G. M. SHELXS-97, Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.
19. [19]
  (19) Luo, G. G.; Wu, S. H.; Pan, Z. H.; Xiao, Z. J.; Dai, J. C. Formation of different polymeric water clusters via organic anionic templates: more carboxylate groups used, more water molecules gathered. Inorg. Chem. Comm. 2014, 39, 34-38.
20. [20]
  (20) Huang, X. Y.; Yue, K. F.; Jin, J. C.; Liu, J. Q.; Wang, C. J.; Wang, Y. Y.; Shi, Q. Z. Three-dimensional fivefold interpenetrating microporous metal-organic framework based on mixed flexible ligands. Inorg. Chem. Commun. 2010, 13, 338-341.
21. [21]
  (21) Kong, Z. G.; Ma, X. Y.; Xu, Z. L.; Wang, X. Y. Synthesis and crystal structure of a new two-dimensional manganese coordination polymer: [Mn(L)(1,4-bdc)]. Chin. J. Struct. Chem. 2011, 30, 927-930.
1. [1]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
2. [2]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
3. [3]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
4. [4]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
9. [9]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
10. [10]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
11. [11]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
12. [12]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
13. [13]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
14. [14]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
15. [15]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
16. [16]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
17. [17]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
18. [18]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
19. [19]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
20. [20]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(718)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142