Citation: LU Jiu-Fu, SHI Juan, ZHENG Nan, GUO Xiao-Hua, GE Hong-Guang. Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 319-325. doi: 10.14102/j.cnki.0254-5861.2011-0814 shu

Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework

1.
Chemical Engineering College, Shaanxi University of Technology, Hanzhong 723001, China

Received Date: 19 May 2015
Available Online: 20 July 2015
Fund Project: This project was supported by the National Natural Science Foundation of China (No. 21373132) (No. 21373132)the Foundation of Shaanxi university of technology (No. SLGKY15-36) (No. SLGKY15-36)

A new coordination polymer, {[Ag₂(bpp)₂(H₂O)₂]·bpdc·3H₂O}_n, derived from the ligand biphenyl-4,4'-dicarboxylic acid (H₂bpdc), has been obtained through a hydrothermal technique (bpp = 1,3-bis(4-pyridyl)propane). Its single-crystal structure has been characterized by single-crystal X-ray diffraction, powder XRD, FT-IR, TGA and elemental analysis techniques. The single-crystal X-ray diffraction reveals that complex 1 consists of 1D infinite [Ag(bpp)(H₂O)]_nⁿ⁺ cationic chains, 2D anionic layer constructed by bpdc anions and free water which provide charge compensation in the crystal structure. The 1D infinite [Ag(bpp)(H₂O)]_nⁿ⁺cationic chains and 2D anionic layer are further stacked in -ABAB- fashion through intermolecular H-bonding to form a 3D sandwich-like framework. In addition, the luminescent property of complex 1 in the solid state at room temperature was investigated.
- Ag(Ⅰ) coordination polymer,
- crystal structure,
- luminescent property
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沈阳化工大学材料科学与工程学院沈阳 110142