Citation: LIU Xiao-Bing, YU Ya-Mei, GE Ming, CUI Guang-Hua. A New Two-dimensional Cobalt(Ⅱ) Coordination Polymer Based on 1,4-Cyclohexanedicarboxylate and Flexible Bis(thiabendazole) Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1749-1755. doi: 10.14102/j.cnki.0254-5861.2011-0784 shu

A New Two-dimensional Cobalt(Ⅱ) Coordination Polymer Based on 1,4-Cyclohexanedicarboxylate and Flexible Bis(thiabendazole) Ligands

a.
a. College of Chemical Engineering, North China University of Science and Technology, Tangshan, Hebei 063009, China;
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b. The Fifth Geology Company of Hebei Geology and Minerals Bureau, Tangshan, Hebei 063000, China

Corresponding author: CUI Guang-Hua,
Received Date: 24 April 2015
Available Online: 3 June 2015
Fund Project: The project was supported by the National Natural Science Foundation of China (51474086) (51474086)

We successfully synthesized a new cobalt(Ⅱ) coordination polymer under hydro-thermal conditions, [Co(L)_0.5(chdc)(H₂O)]_n (L=1,4-bis(thiabendazole)butane, H₂chdc=1,4-cyclo-hexanedicarboxylic acid), which were then characterized by elemental analyses, TG, IR spectro-scopy and single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P2₁/c with a=10.2855(12), b=9.3606(11), c=20.436(3) Å, β=91.573°, V=1966.8(4) Å³, Z=4, C₂₀H₂₂CoN₃O₅S, M_r=475.40, D_c=1.605 g/cm³, μ=1.018 mm^-1 and F(000)=984. The complex possesses a uninodal three-connected hcb Shubnikov hexagonal plane structure with {6³} topology. These planes are further linked into a 3D supramolecular network via O-H…O hydrogen bonds involving coordinated water molecules and oxygen atoms of chdc^2- ligands. The fluorescence and catalytic activities of the complex for degradation of Congo red in a Fenton-like process were investigated.
- catalytic property,
- Co(Ⅱ) complex,
- crystal structure,
- fluorescence
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