Citation: HAN Qian, GUO Sheng-Nan, WANG Xiu-Yan. A New 3D Pb(Ⅱ) Coordination Polymer [Pb(L)]_n Based on a Long Flexible Octane-1,8-dicarboxylic Acid: Crystal Structure and Physical Properties[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1756-1760. doi: 10.14102/j.cnki.0254-5861.2011-0757 shu

A New 3D Pb(Ⅱ) Coordination Polymer [Pb(L)]_n Based on a Long Flexible Octane-1,8-dicarboxylic Acid: Crystal Structure and Physical Properties

HAN Qian ^a,b ,
GUO Sheng-Nan ^a,b ,
WANG Xiu-Yan ^a,b,,

a.
a. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Sipin, Jilin 136000, China;
b.
b. Department of Chemistry, Jilin Normal University, Sipin, Jilin 136000, China

Corresponding author: WANG Xiu-Yan,
Received Date: 9 April 2015
Available Online: 7 July 2015
Fund Project: Supported by the Institute Foundation of Siping City (No. 2013036) (No. 2013036)

A new Pb(Ⅱ)-based coordination polymer, [Pb(L)]_n (1), was hydrothermally synthesized and its structure was determined by single-crystal X-ray diffraction (H₂L=octane-1,8-dicarboxylic acid). Compound 1 crystallizes in orthorhombic, space group Pnma with a=32.061(4), b=7.2597(8), c=4.8084(5) Å, V=1119.2(2) Å³, Z=4, C₁₀H₁₆O₄Pb, M_r=407.42, D_c=2.418 g/cm³, F(000)=760, μ(MoKa)=15.066 mm^-1, R=0.0270 and wR=0.0666. In 1, each Pb(Ⅱ) cation is coordinated by six carboxylate oxygen atoms from four L^2- anions. Each L^2- anion bridges three Pb(Ⅱ) atoms in a μ₃:η²:η¹:η¹ mode to form a 3D framework. The structure of 1 was characterized by IR spectrum and thermogravimetric analysis. Moreover, solid state luminescent property of 1 was also investigated.
- crystal structure,
- Pb(Ⅱ)-based coordination polymer,
- octane-1,8-dicarboxylic acid,
- luminescent property
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