Citation: XIE Yi-Ming ZHAO Yong-Ting. Three Lanthanide Coordination Polymers Based on Novel Rigid Tetracarboxylate Ligand: Syntheses, Crystal Structures, and Luminescence Properties[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1723-1728. doi: 10.14102/j.cnki.0254-5861.2011-0743 shu

Three Lanthanide Coordination Polymers Based on Novel Rigid Tetracarboxylate Ligand: Syntheses, Crystal Structures, and Luminescence Properties

XIE Yi-Ming ZHAO Yong-Ting

1.
College of Materials Science and Engineering, Huaqiao University, Quanzhou, Fujian 362021, China

Received Date: 31 March 2015
Available Online: 10 August 2015
Fund Project: This project was supported by the Fundamental Research Funds for the Central Universities (JB-ZR1119) (JB-ZR1119) the Research Foundation for Talented Scholars (09BS518, 13B0095) (09BS518, 13B0095) the NSF of Fujian Province (Nos. 2013J01237) (Nos. 2013J01237)the Educational Office of Fujian Province (JA12010) (JA12010)

Three lanthanide coordination polymers [Ln(bcpb)_0.5(NO₃)(DEF)₂] (Ln=Y (1), Tb (2), Eu (3), H₄bcpb=2,5-bis(2,4-dicarboxyphenyl) pyridine and DEF=N,N-diethylformamide)) have been solvothermally synthesized under hydrothermal conditions with a novel H₄bcpb ligand and trivalent lanthanide nitrates. Single-crystal X-ray diffraction analysis reveals that compounds 1~3 are isostructural and crystallize in the monoclinic system, space group P2₁/n. Crystal data for 1: C₂₀H₂₆N₄O₉Y, M_r=555.36, a=13.022(9), b=17.778(12), c=10.861(8) Å, β=100.208(3)°, V=2475(3) Å³, Z=4; Crystal data for 2: C₂₀H₂₆N₄O₉Tb, M_r=625.37, a=13.0476(4), b=17.8037(7), c=10.9398(3) Å, β=100.008(4)°, V=2496.4(12) Å³, Z=4; Crystal data for 3: C₂₀H₂₆N₄O₉Eu, M_r=618.41, a=13.055(4), b=17.833(5), c=10.893(3) Å, β=100.133(4)°, V=2496.4(12) Å³, Z=4. The compounds were characterized by thermogravimetric analysis (TGA), IR spectroscopy, and X-ray single-crystal diffraction. Compounds 1~3 all feature 2D networks with -ABAB-fashions. The luminescent properties of compounds 1~3 and free H₄bcpb ligand were investigated at room temperature. The results show that the H4bcpb ligand can efficiently transfer energy to the Tb(Ⅲ) ions, while the energy is not fully transferred from the H₄bcpb ligand to the Eu(Ⅲ) ions.
- lanthanide coordination polymers,
- luminescence,
- topology,
- crystal structure,
- solvothermal
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