Citation: QIN Ye-Yan, YANG Jin-Xia, ZHANG Xin, YE Run-Ping, YAO Yuan-Gena. Two Interpenetrated Dia-type Coordination Polymers Constructed from Mixed Dicarboxylate and Bis(imidazol)-based Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1717-1722. doi: 10.14102/j.cnki.0254-5861.2011-0740 shu

Two Interpenetrated Dia-type Coordination Polymers Constructed from Mixed Dicarboxylate and Bis(imidazol)-based Ligands

a.
a. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
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b. University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: YAO Yuan-Gena,
Received Date: 27 March 2015
Available Online: 6 May 2015
Fund Project: Supported by the 973 Program of China (2011CBA00505) (2011CBA00505) the "Strategic Priority Research Program" of the Chinese Academy of Sciences (XDA07070200, XDA09030102) (XDA07070200, XDA09030102)

Two novel interpenetrating diamond frameworks, namely [Cd(mal)(bix)]_n (1) and {[Zn(sub)(bib)]_n·H₂O}_n (2) (H₂mal=maleic acid, H₂sub=suberic acid, bix=1,4-bis(imidazol-1-ylmethyl)-benzene, bib=1,4-bis(N-imidazolyl)butane) were hydrothermally synthesized and characterized by elemental analysis, infrared spectra (IR), and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the orthorhombic system with space group Pnma and features a 3-fold interpenetrating diamond framework. Compound 2 exhibits a 4-fold interpenetrating diamond network. The luminescent properties of these two compounds have also been investigated in detail.
- cadmium,
- flexible ligand,
- diamondoid network,
- fluorescent property
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