Citation: WU Li-Jian, LI Xin-Xiong, WANG Rui-Hu. Synthesis and Characterization of a Silver(I)-indium(Ⅲ) Heterometallic Metal-organic Framework Based on Nicotinate[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1703-1708. doi: 10.14102/j.cnki.0254-5861.2011-0729 shu

Synthesis and Characterization of a Silver(I)-indium(Ⅲ) Heterometallic Metal-organic Framework Based on Nicotinate

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a. College of Chemistry, Fuzhou University, Fuzhou 350116, China;
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b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 24 March 2015
Available Online: 13 May 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21401195) (No. 21401195)

A heterometallic metal-organic framework, AgIn(nicotinate)₄·1.5DMF, was obtain-ed from the reaction of nicotinic acid, AgNO₃ and In(NO₃)₃ in DMF. The complex was characterized by elemental analysis, infrared spectrum, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. Crystal data are: C_28.5H_26.5N_5.5O_9.5AgIn, orthorhombic space group I222, a=10.775(15), b=11.939(18), c=13.93(2) Å, V=1792(5) Å³, Z=2, D_c=1.521 mg/m³, μ=1.244 mm^-1, F(000)=816, the final R=0.0672 and wR=0.1812 for 1912 observed reflections with I>2σ(I). Single-crystal X-ray structure analysis reveals that nicotinate bridges In(Ⅲ) and Ag(I) through carboxylate chelating with In(Ⅲ) and pyridyl nitrogen atom coordinating to Ag(I), generating a new 2D network consisting of tetrahedral building units of [AgN4]⁺ and [In(COO)4]^-.
- indium,
- silver,
- heterometallic MOF,
- nicotinic acid,
- crystal structure
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