Citation: CUI Yi-Xin, YANG Wen-Bin, XIE Xing-Kun, WU Xiao-Yuan, LU Can-Zhong. Synthesis, Structure and Properties of a New Silver Nitrate Complex[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1697-1702. doi: 10.14102/j.cnki.0254-5861.2011-0726 shu

Synthesis, Structure and Properties of a New Silver Nitrate Complex

a.
a. College of Chemistry, Fuzhou University, Fuzhou 35002, China;
b.
b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 23 March 2015
Available Online: 20 April 2015
Fund Project: This project was supported by the Natural Science Foundation of Fujian Province (2012J06006, 2006L2005) (2012J06006, 2006L2005)

A new metal-organic coordination polymer, [Ag(L)(NO₃)]_n (1, L=β-amino-β-(pyrid-2-yl)acrylonitrile), has been synthesized by solvent method at ambient temperature and characterized through single-crystal diffraction, Fourier transformed infrared spectrum (FTIR), elemental analysis, thermogravimetry analysis (TGA) and fluorescent measurements. 1 crystallizes in the triclinic system, space group P1 with a=7.3600(3), b=8.5095(17), c=9.2936(14) Å, α=66.65(6), β=70.56(7), γ=71.59(6)°, V=492.4(4) Å³, μ=2.043 mm^-1, D_c=2.104 Mg/m³, Z=2, M_r=312.01, F(000)=302, the final R=0.0347 and wR=0.0987 for 3924 observed reflections with I>2σ(I).
- four-coordinate Ag(I) complex,
- crystal structure,
- photoluminescence
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