Citation: WANG Nan-Nan, HE Zhang-Zhen, GUO Wen-Bin, ZHANG Su-Yun, YANG Ming, TANG Ying-Ying. Structure and Magnetic Properties of a New Oxohalogenide Compound Ba7CoV6O21Cl4[J]. Chinese Journal of Structural Chemistry, ;2015, 34(9): 1357-1361. doi: 10.14102/j.cnki.0254-5861.2011-0711
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A new oxohalogenide compound Ba7CoV6O21Cl4 was synthesized by a conventional high-temperature solid state reaction. The title compound is found to crystallize in the orthorhombic system of space group Cmcm with a=16.726(4), b=10.568(3), c=14.808(4) Å, V=2617.4(12) Å3, Z=2, Mr=1803.68, Dc=3.411 g/cm3, μ=11.396 mm-1, F(000)=3172, the final R=0.0314 and wR=0.0750 for 1531 observed reflections with I>2σ(I). Co2+ ions are coordinated by four O and two Cl atoms, forming a CoO4Cl2 octahedron, while V atoms are tetrahedrally coordinated, forming (V2O7)4- groups. The structure of Ba7CoV6O21Cl4 exhibits a pseudo-onedimensional chain running along the c-axis. Magnetic measurements confirm that Ba7CoV6O21Cl4 shows a paramagnetic behavior down to 2 K.
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Keywords:
- oxohalogenide,
- crystal structure,
- solid-state reaction,
- magnetism
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