Citation: WANG Nan-Nan, HE Zhang-Zhen, GUO Wen-Bin, ZHANG Su-Yun, YANG Ming, TANG Ying-Ying. Structure and Magnetic Properties of a New Oxohalogenide Compound Ba₇CoV₆O₂₁Cl₄[J]. Chinese Journal of Structural Chemistry, ;2015, 34(9): 1357-1361. doi: 10.14102/j.cnki.0254-5861.2011-0711 shu

Structure and Magnetic Properties of a New Oxohalogenide Compound Ba₇CoV₆O₂₁Cl₄

WANG Nan-Nan ^a,b ,
HE Zhang-Zhen ^b,, ,
^b ,
GUO Wen-Bin ^b ,
ZHANG Su-Yun ^b ,
YANG Ming ^b ,
TANG Ying-Ying ^b

1.
a College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: HE Zhang-Zhen,
Received Date: 16 March 2015
Available Online: 11 May 2015
Fund Project: This project was supported by the MOST projects, the National Basic Research Program of China (No.2012CB921701) (No.2012CB921701)National Natural Science Foundation of China (No.21403234) (No.21403234)

A new oxohalogenide compound Ba₇CoV₆O₂₁Cl₄ was synthesized by a conventional high-temperature solid state reaction. The title compound is found to crystallize in the orthorhombic system of space group Cmcm with a=16.726(4), b=10.568(3), c=14.808(4) Å, V=2617.4(12) Å³, Z=2, M_r=1803.68, D_c=3.411 g/cm³, μ=11.396 mm^-1, F(000)=3172, the final R=0.0314 and wR=0.0750 for 1531 observed reflections with I>2σ(I). Co²⁺ ions are coordinated by four O and two Cl atoms, forming a CoO₄Cl₂ octahedron, while V atoms are tetrahedrally coordinated, forming (V₂O₇)^4- groups. The structure of Ba₇CoV₆O₂₁Cl₄ exhibits a pseudo-onedimensional chain running along the c-axis. Magnetic measurements confirm that Ba₇CoV₆O₂₁Cl₄ shows a paramagnetic behavior down to 2 K.
- oxohalogenide,
- crystal structure,
- solid-state reaction,
- magnetism
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