Citation: WU Gang, QIN Cheng-Song, WANG Xiao-Feng. Synthesis, Crystal Structure and Properties of Barium Coordination Compound Based on 1,3,5-Benzenetricarboxylic Acid Ligand[J]. Chinese Journal of Structural Chemistry, ;2015, 34(9): 1391-1398. doi: 10.14102/j.cnki.0254-5861.2011-0678 shu

Synthesis, Crystal Structure and Properties of Barium Coordination Compound Based on 1,3,5-Benzenetricarboxylic Acid Ligand

1.
a College of Material and Chemical Engineering, Chuzhou University, Chuzhou, Anhui 239012, China;
2.
b College of Environmental Science, Xiaozhuang University, Nanjing 211171, China

Received Date: 10 February 2015
Available Online: 15 April 2015
Fund Project: This project was supported by the National Natural Science Foundation of China (41472047) (41472047)Science Research Starting Project of Chuzhou University (2014qd035) (2014qd035)

A new coordination polymer [Ba₃(btc)₂(H₂O)₈]·2H₂O (1, H₃btc=1,3,5-benzenetricarboxylic acid) has been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and infrared spectroscopy analysis. All carboxylate oxygen atoms of btc³⁻ participate in coordination with the central Ba(II) ions. The Ba(1) center is eight-coordinated with a distorted square antiprismatic coordination geometry, while the Ba(2) ion is ten-coordinated with a distorted dicapped square prism. Three carboxyl groups of the anion btc^3- take μ₂-η¹:η¹ and μ₂-η²:η¹ coordination modes, respectively. The whole btc^3- anion acts as a μ₆-bridge connecting six different Ba(II) ions to form a 3D framework structure. Luminescent and thermal stable properties of complex 1 were investigated.
- 1,3,5,-benzenetriarboxylic acid,
- crystal structure,
- barium
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