Citation: HAO Xiao-Min, GU Chang-Sheng, JI Li-Li, HU Shi-Wei, LI Yong, SONG Wen-Dong. Syntheses and Crystal Structures of Three Ag(I) Complexes with Chloro-phenylacetic Acid and Nitrogen Heterocyclic Ligand[J]. Chinese Journal of Structural Chemistry, ;2015, 34(9): 1362-1370. doi: 10.14102/j.cnki.0254-5861.2011-0670 shu

Syntheses and Crystal Structures of Three Ag(I) Complexes with Chloro-phenylacetic Acid and Nitrogen Heterocyclic Ligand

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a Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, Guangdong 524088, China;
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b Innovation & Application Institute, Zhejiang Ocean University, Zhoushan, Zhejiang 316022, China

Corresponding author: GU Chang-Sheng, SONG Wen-Dong,
Received Date: 6 February 2015
Available Online: 11 May 2015
Fund Project:

Three new coordination polymers {[Ag₂(2,4-DCPA)(4,4'-bipy)₂(NO₃)]·(H₂O)}_n (1), [Ag(2,4-DCPA)(bpp)]_n (2) and {[Ag(4-DCPA)(bpp)]·(H₂O)}_n (3), were synthesized by evaporation methods using 2,4-dichlorophenylacetic acid (2,4-DCPA), 4-chlorophenylacetic acid (4-DCPA), 4,4'-dipyridyl (4,4'-bipy), 1,3-bis(4-pyridyl)propane(bpp) and AgNO₃. Compound 1 crystallizes in monoclinic, space group P2₁/c with a=10.035(2), b=17.796(3), c=16.448(2) Å, β=104.086(2)°, V=2705.9(2) Å³, D_c=1.893 g/cm^-3, C₂₈H₂₃Cl₂N₅O₆Ag₂, M_r=812.15, F(000)=1608, μ(MoKα)=1.615 mm^-1, Z=4, R=0.0310, wR=0.0832 for 4357 observed reflections (I>2σ(I)), and R=0.0362, wR=0.0873 for all data. Compound 3 crystallizes in monoclinic, space group P2₁/c with a=9.840(2), b=24.971(5), c=9.3301(2) Å, β=117.504(2)°, V=2033.5(7) Å³, D_c=1.666 g/cm^-3, C₂₁H₁₉C_l2N₂O₂Ag, M_r=510.15, F(000)=1024, μ(MoKα)=1.273 mm^-1, Z=4, R=0.0315 and wR=0.0680 for 2853 observed reflections (I>2σ(I)) and R=0.0454, wR=0.0736 for all data. Compound 3 crystallizes in monoclinic, space group P2₁/n with a=15.472(4), b=9.000(2), c=16.262(4) Å, β=112.049(4)°, V=2099.0(8) Å³, D_c=1.562 g/cm^-3, C₂₁H₂₂C_lN₂O₃Ag, M_r=493.73, F(000)=1000, μ(MoKα)=1.111 mm^-1, Z=4, R=0.0296, wR=0.0821 for 3059 observed reflections (I>2σ(I)), and R=0.0398, wR=0.0986 for all data. The complexes were characterized by elemental analysis, FT-IR, thermogravimetrie analysis (TGA) and X-ray single-crystal structure analysis. Fluorescence properties of complex 3 and PXRD of 1 and 2 have been studied. As a result, in complex 1, the Ag(I) ion is surrounded by two nitrogen atoms from two bipy ligands to form an infinite chain, and adjacent Ag-bipy chains produce "rungs" of a ladder by silver ions contact. And in complexes 2 and 3, the two-dimensional β-sheet like layers are obtained by Ag···Ag interactions.
- silver complex,
- chloro-phenylacetic acid,
- crystal structure
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