Citation: WANG Ji-Wu, SU Yong-Chao, WANG Ji-Jiang. Synthesis and Characterization of a New 3D Pillared Bilayer Cd(II) Coordination Polymer Based on 6,6'-Dinitro-2,2',4,4'-biphenyltetracarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2015, 34(9): 1385-1390. doi: 10.14102/j.cnki.0254-5861.2011-0666 shu

Synthesis and Characterization of a New 3D Pillared Bilayer Cd(II) Coordination Polymer Based on 6,6'-Dinitro-2,2',4,4'-biphenyltetracarboxylic Acid

1.
a Department of Chemical Engineering, Yulin Vocational and Technical College, Yulin 719300, China;
2.
b Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an 716000, China

Corresponding author: WANG Ji-Jiang,
Received Date: 4 February 2015
Available Online: 22 April 2015
Fund Project: This project was supported by the National Natural Science Foundation of China (No.21373178) (No.21373178)

A new 3D Cd(II) coordination polymer, [Cd₂L(dpe)]_n (1, H₄L=6,6'-dinitro-2,2',4, 4'-biphenyltetracarboxylic acid, dpe=1,2-di(4-pyridyl)ethylene), has been synthesized using the hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analysis, IR, thermogravimetric analysis, and photoluminescent analysis. Complex 1 crystallizes in the monoclinic system, space group C2/c with a=8.0006(15), b=23.900(5), c=14.836(3) Å, β=95.723(3)°, V=2822.7(10) Å³, Z=8, D_c=1.937 Mg·m^-3, μ=1.581 mm^-1, F(000)=1608, the final R=0.0231 and wR=0.0629 for 2239 observed reflections with I>2σ(I). Complex 1 is a 3D pillared bilayer (4,5,7)-connected net with the Schläfli symbol of (4¹⁴·6⁷) (4²·6⁵·8³) (4⁴·6²) topology. The photoluminescent property of 1 is also investigated.
- coordination polymer,
- 6,6'-dinitro-2,2',4,4'-biphenyltetracarboxylic acid,
- Cd(II)
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