Citation: HOSSEIN Shirdel, FARZIN Marandi, ABBAS Jalilzadeh, SEBASTIAN Huber, ARNO Pfitzner. Effects of Direction of Bridging of Thiocyanato on the Dimension of Coordination Polymers: Synthesis, Characterization and Single-crystal X-ray Structure Determination of [Cd(4,4'-dm-2,2'-bpy)(NCS)₂]_n and [Cd(4,4'-dmo-2,2'-bpy)(NCS)₂]_n Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1135-1144. doi: 10.14102/j.cnki.0254-5861.2011-0662 shu

Effects of Direction of Bridging of Thiocyanato on the Dimension of Coordination Polymers: Synthesis, Characterization and Single-crystal X-ray Structure Determination of [Cd(4,4'-dm-2,2'-bpy)(NCS)₂]_n and [Cd(4,4'-dmo-2,2'-bpy)(NCS)₂]_n Coordination Polymers

a.
a. Department of Food Industry, Maku Branch, Islamic Azad University, Maku, Iran;
b.
b. Department of Chemistry, Payame Noor University, Tehran, Iran;
c.
c. Institut für Anorganische Chemie, Universitaet Regensburg 93040, Regensburg, Germany

Corresponding author: HOSSEIN Shirdel,
Received Date: 2 February 2015
Available Online: 14 April 2015
Fund Project:

Two new cadmium(Ⅱ)-thiocyanato coordination polymers with 4,4'-dimethyl-2,2'-bipyridine (4,4'-dm-2,2'-bpy) and 4,4'-dimethoxy-2,2'-bipyridine (4,4'-dmo-2,2'-bpy) as chelating ligands were synthesized and characterized by elemental analysis, IR and ¹H NMR spectroscopy and X-ray crystallography. Thermal properties were also studied as well. These complexes have formed as [Cd(4,4'-dm-2,2'-bpy)(NCS)₂]_n (1) and [Cd(4,4'-dmo-2,2'-bpy)(NCS)₂]_n (2). The coordination numbers of Cd^Ⅱ in 1 and 2 are six (CdN₄S₂). Direction of bridging of thiocyanato anions in 1 and 2 created one- and two-dimensional coordination polymers, respectively. The supramolecular features in these complexes were guided and controlled by weak directional intermolecular interactions.
- 2,2'-bipyridine,
- cadmium(Ⅱ),
- coordination polymer,
- weak interactions
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