Citation: HU Qi-Chang, LIN Wen-Wen, CHEN Ye-Qing, HUANG Feng. Subsolidus Phase Relations in the ZnO-MoO₃-Bi₂O₃ System[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1056-1062. doi: 10.14102/j.cnki.0254-5861.2011-0659 shu

Subsolidus Phase Relations in the ZnO-MoO₃-Bi₂O₃ System

1.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: HUANG Feng,
Received Date: 29 January 2015
Available Online: 1 May 2015
Fund Project: and the Natural Science Foundation of Fujian Province (2012J05033) (No. 91333207)

The subsolidus phase relations of the ternary system ZnO-MoO₃-Bi₂O₃ have been investigated by X-ray diffraction (XRD) analyses. The phase diagrams have been constructed. There are eight binary compounds and no ternary compound in the ZnO-MoO₃-Bi₂O₃ system. This system can be divided into nine three-phase regions. From the phase relations of ZnO-MoO₃-Bi₂O₃ system, the possible component regions for ZnO single crystal flux growth are ZnO-Zn₃Mo₂O₉-Bi₂MoO₆, ZnO-Bi₂MoO₆-Bi₂₆Mo₁₀O₆₉, ZnO-Bi₂₆Mo₁₀O₆₉-Bi₁₄MoO₂₄, and ZnO-Bi₁₄MoO₂₄-Bi₃₈ZnO₅₈.
- ZnO-MoO₃-Bi₂O₃ system,
- ZnO crystal growth,
- phase diagram,
- X-ray diffraction
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