Citation: WANG Hao, XING Guang-Jian, CHEN Fei, SUN Jie, ZHANG Ying-Hui. Metal-directed Assembly of Two Distinct Coordination Polymers with 2,5-Furandicarboxylic Acid and 4,4'-Bipyridine[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1113-1120. doi: 10.14102/j.cnki.0254-5861.2011-0618 shu

Metal-directed Assembly of Two Distinct Coordination Polymers with 2,5-Furandicarboxylic Acid and 4,4'-Bipyridine

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a. Beijing Key Lab of Special Elastomer Composite Materials, College of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China;
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b. College of Chemistry, Key Laboratory Advanced Energy Materials Chemistry(Ministry of Education), Nankai University, Tianjin 300071, China

Received Date: 29 December 2014
Available Online: 28 April 2015
Fund Project: The work was supported by URT program of Beijing Institute of Petrochemical Technology (Beijing municipal level 2015J00058) (Beijing municipal level 2015J00058)URT program of Beijing Institute of Petrochemical Technology (State level 2015J00056) (State level 2015J00056)

By using solvothermal method, two new metal coordination polymers based on 2,5-furandicarboxylic acid (H₂FDA) ligand and 4,4'-bipyridine (bipy), [Cu(FDA)(4,4'-bipy)(DMF)]_n·solvent (1) and {[Zn(4,4'-bipy)(FDA)(DMF)]·DMF}_n (2), were produced and characterized by single-crystal X-ray diffraction analyses, elemental analyses, IR and powder X-ray diffraction. Compound 1 crystallizes in monoclinic space group P2₁/c with a=11.104(2), b=10.396(2), c=18.772(4)Å, β=96.20(3)°, V=2154.2(7)Å³, D_c=1.378 g/cm³, C₁₉H₁₇CuN₃O₆, M_r=446.90, F(000)=916, μ(MoKα)=1.05 mm^-1, Z=4, R=0.0691 and wR=0.1341 for 3537 observed reflections (I>2σ(I)), and R=0.1062 and wR=0.1482 for all data. Compound 2 crystallizes in monoclinic space group C2/c with a=29.779(6), b=9.6417(19), c=17.292(3)Å, β=105.69(3)°, V=4779.9(16)Å³, D_c=1.445 g/cm³, C₂₂H₂₂N₄O₇Zn, M_r=519.81, F(000)=2144, μ(MoKα)=1.08 mm^-1, Z=8, R=0.0641 and wR=0.1007 for 2985 observed reflections (I>2σ(I)), and R=0.1028 and wR=0.1112 for all data. Different coordination geometry of metal ions, square pyramid of Cu²⁺ and trigonal bipyramid of Zn²⁺, bring about different orientations of FDA^2- ligands as well as 4,4'-bipyridine ligands, and furthermore distinct assembly structures for 1 and 2. The thermal stabilities of 1 and 2 are also investigated.
- 2,5-furandicarboxylic acid,
- 4,4'-bipyridine,
- metal-directed,
- coordination polymer
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