Citation: HU Jiu-Rong, YAN Wei-Hong, LUO Nian-Hua, DONG Rou-Jie, HUANG Rong-Li, YE Hong-De. Synthesis, Crystal Structure and Catalytic Activity of a Bimetallic Rhodium Complex with 1,5-Cyclooctadiene and 2,2'-Bipyridine[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1107-1112. doi: 10.14102/j.cnki.0254-5861.2011-0613 shu

Synthesis, Crystal Structure and Catalytic Activity of a Bimetallic Rhodium Complex with 1,5-Cyclooctadiene and 2,2'-Bipyridine

a.
a. Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Jiangxi 334001, China;
b.
b. School of Biology and Chemical Engineering, Nanyang Institute of Technology, Nanyang 473004, China

Corresponding author: HU Jiu-Rong,
Received Date: 24 December 2014
Available Online: 26 March 2015
Fund Project:

A new complex [Rh(COD)(2,2'-bipy)]·[Rh(COD)Cl₂] (COD=1,5-cyclooctadiene, 2,2'-bipy=2,2'-bipyridine) has been synthesized and characterized by elemental analyses, NMR and single-crystal X-ray diffraction. The complex crystallizes in triclinic system, space group P1 with a=7.4782(14), b=10.1400(11), c=16.6982(14)Å, α=103.494(11), β=91.996(13), γ=103.829(12)°, C₂₆H₃₂Cl₂N₂Rh₂, M_r=649.26, V=1190.0(3)Å³, D_c=1.812 g/cm³, Z=2, F(000)=652, μ(MoKα)=1.629 mm^-1, R=0.0286 and wR=0.0463 for 3718 observed reflections (I>2σ(I)). The complex was linked to form 1D chains by hydrogen bonding interaction (C-H…Cl), and further to construct a 2D layer structure by π…π stacking interactions between the pyridine rings of 2,2'-bipy ligands. The hydroformylation catalyzed by the title complex was also studied.
- Rh(I) complex,
- 2,2'-bipyridine,
- crystal structure,
- hydroformylation
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