Citation: CHEN Jun-Ling, FENG Xun, XIE Shi-Yu, WANG Cai-Lu, WANG Li-Ya, LANG Xue-Ming. Synthesis, Structure and Characterization of a 3d-4f Hetero-metallic Complex Based on Imidazole-dicarboxylate[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 771-776. doi: 10.14102/j.cnki.0254-5861.2011-0606 shu

Synthesis, Structure and Characterization of a 3d-4f Hetero-metallic Complex Based on Imidazole-dicarboxylate

CHEN Jun-Ling ^a ,
FENG Xun ^b,, ,
XIE Shi-Yu ^b ,
WANG Cai-Lu ^a ,
WANG Li-Ya ^a,b,, ,
LANG Xue-Ming ^b

1.
a School of Life Science and Technology, Nanyang Normal University, Nanyang 473061, China;
2.
b College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: FENG Xun, WANG Li-Ya,
Received Date: 18 December 2014
Available Online: 5 February 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No.21273101) (No.21273101) Program for Science & Technology Innovation Talents in Universities of Henan (2014HASTIT014) (2014HASTIT014) Key program of Foundation of Education Committee of Henan Province (No.14B150033) (No.142102310483) and Graduate Innovation Foundation Project of Nanyang Normal University (No.20141110) (No.14B150033)

A new 3d-4f polymer formulated as {[SmCo₂(μ₂-Hmimda)₃(μ₂-H₂mimda)·4H₂O]·3H₂O}_n (H₃mimda=1-H-2-methyl-4,5-imidazole-dicarboxylic acid) has been hydrothermally synthesized and structurally characterized by elemental analysis, X-ray single-crystal diffraction and magnetic susceptibility measurement. It crystallizes in monoclinic system, space group C2/c, with a=17.251(6), b=16.965(6), c=14.668(5) Å, β=118.565(5)°, Z=4, V=3770(2) Å³, F(000)=1984, the final R=0.0597 and wR=0.1820. In the crystal, the dicarboxylate ligand links the Sm(III) and Co(II) ions to give rise to a heterometallic [SmCo₂(μ₂-Hmimda)₃(μ₂-H₂mimda)] aggregate which acts as the second building unit. Then, the SBUs further extended a 2D corrugated layer with a (4, 4) topology. The title complex displays strong photoluminescence in the solid state.
- H₃mimda,
- X-ray single crystal,
- magnetic susceptibility,
- photoluminescence
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