Citation: JIA Wei-Guo, DAI Yuan-Chen, LI Dan-Dan, WANG Dong-Sheng, SHENG En-Hong. Zinc Complexes Based on Organochalcogen Ligand Mbit: Syntheses, Structures and Photocatalytic Properties[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1099-1106. doi: 10.14102/j.cnki.0254-5861.2011-0597 shu

Zinc Complexes Based on Organochalcogen Ligand Mbit: Syntheses, Structures and Photocatalytic Properties

1.
College of Chemistry and Materials Science, Center for Nano Science and Technology, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-based Materials, Anhui Normal University, Wuhu 241000, China

Corresponding author: JIA Wei-Guo, SHENG En-Hong,
Received Date: 8 December 2014
Available Online: 2 June 2015
Fund Project: This work was financially supported by the National Natural Science Foundation of China (21102004) (21102004) and Training Programs of Innovation and Entrepreneurship of Anhui Province for Undergraduates (AH₂01410370040) (201410370040)

The zinc complex with neutral organochalcogen ligand Mbit, [(Mbit)₂Zn](ClO₄)₂ (1, Mbit=1,1'-methylenebis(3-methyl-imidazole-2-thione)), has been synthesized and characterized. The complex has been characterized by elemental analysis, NMR and IR spectra. The molecular structure of 1 has been determined by X-ray crystallography. For the complex, C₁₈H₂₄Cl₂N₈O₈S₄Zn, M_r=744.96, triclinic, space group P1, a=11.2923(18), b=11.9353(19), c=13.837(3)Å, α=114.763(2), β=92.132(2), γ=116.039(2)°, V=1464.6(5)Å³, Z=2, D_c=1.689 g/cm³, λ=1.54184Å, μ=1.363 mm^-1, F(000)=760, S=1.098, the final R=0.0554 and wR=0.0.1579. Complex 1 exhibits photocatalytic activity for methyl orange (MO) degradation under UV light and shows good stability toward photocatalysis.
- zinc,
- organochalcogen,
- structure,
- photocatalytic
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