Citation: XIA Yan-Fei, YANG En-Cui, LIU Zhong-Yi, ZHAO Xiao-Jun. A New 2-Naphthate-based Layered Complex with Unusual Corner-sharing Triangular Magnetic Lattice[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 703-709. doi: 10.14102/j.cnki.0254-5861.2011-0578 shu

A New 2-Naphthate-based Layered Complex with Unusual Corner-sharing Triangular Magnetic Lattice

1.
a College of Chemistry, Key Laboratory of Inorganic-organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, China;
2.
b Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, China

Received Date: 18 November 2014
Available Online: 14 February 2015
Fund Project:

A new 2-naphthate (NA^-)-based coordination complex, [Cu₃(µ₃-OH)₄(NA)₂]_n (1), was hydrothermally prepared and structurally and magnetically characterized. 1 crystallizes in the monoclinic P2₁/c space group with a=19.990(7), b=5.616(2), c=9.179(3) Å, β=96.536(6)°, V=1023.8(7) Å³, D_c=1.950 g/cm³, M_r=300.49, Z=4, F(000)=602, μ=3.138 mm^-1, the final R=0.0317 and wR=0.0818 for 4944 observed reflections with I>2σ(I). Complex 1 exhibits an extended corner-sharing {Cu₃(µ₃-OH)}⁵⁺ triangle-based layered structure with the NA^- ligands located on both sides. The interplay of the typical anti- and ferromagnetic interactions mediated by µ₃-OH^- and µ-syn, syn-carboxylate heterobridges leads to the overall intralayer ferromagnetic couplings of 1.
- 2-naphthoic acid,
- corner-sharing triangle,
- crystal structure,
- magnetic lattice
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