Citation: WANG Xiao-Bing, LU Zheng-An, LU Wen-Guan. A 2D Brickwall-like Copper(II) Coordination Polymer Based on Phenyliminodiacetate and 4,4'-Bipyridine: Synthesis, Crystal Structure and Magnetic Property[J]. Chinese Journal of Structural Chemistry, ;2015, 34(9): 1410-1416. doi: 10.14102/j.cnki.0254-5861.2011-0553 shu

A 2D Brickwall-like Copper(II) Coordination Polymer Based on Phenyliminodiacetate and 4,4'-Bipyridine: Synthesis, Crystal Structure and Magnetic Property

1.
Department of Chemistry, Shaoguan University, Shaoguan 512005, China

Received Date: 30 October 2014
Available Online: 18 December 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (No.21071099) (No.21071099)

A novel copper(II) coordination polymer of {[Cu₃L₂(4,4'-bipy)₄](ClO₄)₂·20H₂O}_n (1) was synthesized by the reaction of H₂L (C₆H₅N(CH₂COOH)₂, phenyliminodiacetic acid), CuSO₄·5H₂O, NaClO₄·H₂O and 4,4'-bipy (4,4'-bipyridine) in water/methanol, followed by slow evaporating at room temperature. The compound was characterized by elemental analysis (EA), infrared spectroscopy (IR), thermogravimetric analysis (TGA) and single-crystal/powder X-ray diffraction. The result of single-crystal X-ray diffraction analysis reveals that 1 crystallizes in the monoclinic crystal system with C2/c space group, a=2.9974(4), b=1.7270(2), c=2.0007(3) nm, β=128.793(2)°, V=8.0722(19) nm³, Z=4, D_c=1.472 g·cm⁻³, μ=0.942 mm⁻¹, F(000)=3716, R=0.0487 and wR=0.1204 (I>2σ(I)). The basic structural unit of 1 is a trinuclear cluster unit of [Cu₃L₂]²⁺, which is constructed by two μ₂-L²⁻ ligands bridging and chelating three Cu(II) ions. These [Cu₃L₂]²⁺ units are connected with each other by 4,4'-bipy ligands to generate a 2D cation brickwall-like network of [Cu₃L₂(4,4'-bipy)₄]_n²ⁿ⁺. These adjacent 2D cation layers are further stacked in a staggered fashion via interlayer stacking interactions to form a 3D supramolecular structure with 1D open square channels, in which the ClO4⁻ counter anions and lattice water molecules are filled. Furthermore, the magnetic property of 1 was also investigated.
- coordination polymers (CPs),
- copper(II) compound,
- crystal structure,
- magnetic property
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