Citation: HUANG Rong-Rong, ZHANG Su-Yun, CUI Mei-Yan, XU Jun, HE Zhang-Zhen. Synthesis, Crystal Structure and Property of CuPb₂(OH)₂Cl₃[J]. Chinese Journal of Structural Chemistry, ;2015, 34(4): 594-598. doi: 10.14102/j.cnki.0254-5861.2011-0552 shu

Synthesis, Crystal Structure and Property of CuPb₂(OH)₂Cl₃

a.
a. College of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430073, China;
b.
b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: HE Zhang-Zhen,
Received Date: 30 October 2014
Available Online: 24 December 2014
Fund Project: This work was financially supported by the National Basic Research Program of China (No. 2012CB921701) (No. 2012CB921701)

A new copper(I)-lead(Ⅱ) oxyhalide, CuPb₂(OH)₂Cl₃, has been prepared by hydrothermal reaction and structurally characterized by single-crystal X-ray analysis. The compound crystallizes in tetragonal, space group I4(1)/acd with a=b=13.77(1), c=15.38(1)Å, V=2916.2(2), Z=4, M_r=618.29, D_c=5.633 g/cm³, μ=49.97(2) mm^-1, F(000)=4192, the final R=0.0204 and wR=0.0452 for 757 observed reflections with I>2σ(I). The structure of CuPb₂(OH)₂Cl₃ contains one-dimensional helical chains built by CuCl₄ tetrahedra with corner-sharing along the c-axis, in which the Pb²⁺ and OH-ions are located at the voids between chains. Optical reflectance spectrum measurements indicate that it is a semiconductor with a band-gap of 3.23 eV.
- oxyhalide,
- crystal structure,
- hydrothermal reaction,
- semiconductor
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