Citation: WANG Xiu-Yan, ZHAO Zhong-Yu, LIU Rui, XU Ye, LI Xin-Hang, XU Zhan-Lin. Synthesis, Crystal Structure and Luminescence of a New Zn(II) Complex [Zn(1,2,3-HBTC)(L)]₂ Constructed by Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 725-728. doi: 10.14102/j.cnki.0254-5861.2011-0545 shu

Synthesis, Crystal Structure and Luminescence of a New Zn(II) Complex [Zn(1,2,3-HBTC)(L)]₂ Constructed by Mixed Ligands

WANG Xiu-Yan ^a,b ,
ZHAO Zhong-Yu ^a,b ,
LIU Rui ^a,b ,
XU Ye ^a,b ,
LI Xin-Hang ^a,b ,
XU Zhan-Lin ^a,b,,

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China;
2.
b Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: XU Zhan-Lin,
Received Date: 24 October 2014
Available Online: 26 December 2014
Fund Project: Supported by the Institute Foundation of Siping City (No.2013036) (No.2013036)

A new Zn(II) complex, [Zn(1,2,3-HBTC)(L)]₂ (1, L=2-(2-chloro-6-fluorophenyl)- 1H-imidazo[4,5-f][1,10]phenanthroline and 1,2,3-H₃BTC=1,2,3-benzentricarboxylic acid), was synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a=10.455(2), b=11.533(2), c=12.499(3) Å, α=116.97(3), β=94.08(3), γ=103.29(3)°, V=1280.2(4) Å³, Z=1, C₅₆H₂₈C_l2F₂N₈O₁₂Zn₂, M_r=1244.50, D_c=1.614 g/cm³, F(000)=628, μ(MoKa)=1.124 mm^-1, R=0.0502 and wR=0.1417. In compound 1, two 1,2,3-HBTC anions bridge two Zn(II) atoms to give a dimeric structure with Zn···Zn distance of 3.15 Å. Adjacent dimers interact through π-π stackings between two L ligands to result in a supramolecular layer. Moreover, N-H···O and O-H···N hydrogen bonds further stabilize the 2D supramolecular architecture of 1. In addition, the luminescent property of 1 has been studied.
- hydrogen bonds,
- crystal structure,
- dimer,
- 1,2,3-benzentricarboxylic acid
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