Citation: YE Yan-Zhu, WU Xin-Jian, WANG A-Lian. Synthesis, Structure and Property of a Novel Coordination Polymer [Tb(C₇H₃NO₄)(C₆H₄NO₂)(H₂O)][J]. Chinese Journal of Structural Chemistry, ;2014, 33(12): 1860-1864. doi: 10.14102/j.cnki.0254-5861.2011-0534 shu

Synthesis, Structure and Property of a Novel Coordination Polymer [Tb(C₇H₃NO₄)(C₆H₄NO₂)(H₂O)]

1.
Department of Science Research and Training Fujian Institute of Education, Fuzhou 350001, China

Corresponding author: YE Yan-Zhu,
Received Date: 13 October 2014
Available Online: 20 November 2014
Fund Project: This work was financially supported by Foundation of Fujian Educational Committee (JA14348) (JA14348)

A novel terbium(Ⅲ) coordination polymer [Tb(C₇H₃NO₄)(C₆H₄NO₂)(H₂O)] was successfully synthesized hydrothermally and characterized by single-crystal X-ray diffraction. The complex is of monoclinic, space group P2₁/c with a=9.2252(11), b=14.1477(16), c=10.5134(12)Å, β=95.770(2)°, V=1365.2(3)Å³, Z=4, D_c=2.248 g·cm^-3, F(000)=880, the final R=0.0176 and wR=0.0411 for 2149 observed reflections with I>2σ(I). The complex is extended into a three-dimensional network structure with 24-atom rings which are composed of Tb, C and O atoms. The complex displays green fluorescence emission in the solid state at room temperature, which corresponds to ⁵D₄→⁷F₅ transition of the Tb(Ⅲ) ion.
- pyridine-2,5-dicarboxylic acid,
- terbium,
- coordination polymer,
- luminescent property
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