Citation: HAO Xiao-Min, GU Chang-Sheng, HAN Si-Yin, MIAO Yan-Li, LI Yong, SONG Wen-Dong. Syntheses and Crystal Structures of Cd(Ⅱ) and Ni(Ⅱ) Complexes Containing Flexible Sulfide and Nitrogen Heterocyclic Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(3): 408-416. doi: 10.14102/j.cnki.0254-5861.2011-0501 shu

Syntheses and Crystal Structures of Cd(Ⅱ) and Ni(Ⅱ) Complexes Containing Flexible Sulfide and Nitrogen Heterocyclic Ligands

a.
a. Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang 524088, China;
b.
b. College of Food Science and Technology, Guangdong Ocean University, Zhanjiang 524088, China;
c.
c. School of Petrochemical & Energy Engineering, Zhejiang Ocean University, Zhoushan 150001, China

Received Date: 9 September 2014
Available Online: 18 November 2014
Fund Project:

Two new coordination polymers [Cd(EBLA)(ip)(H₂O)] (1) and [Ni(EBSA) (im)₂(H₂O)]_n (2) were synthesized by hydrothermal and solution methods using 2,2'-dithiosalicylicacid (EBSA), 1H-imidazo[4,5-f][1,10]phenanthroline (ip), imidazole (im), Cd(NO₃)₂·4H₂O and Ni(NO₃)₂·6H₂O. The complexes were characterized by elemental analysis and FT-IR. Meanwhile, the crystal structures, fluorescence properties of complex 1 and thermogravimetrie analysis of complex 2 have been studied. In complex 1, 2,2'-dicarboxydiphenylthioether (EBLA) was prepared with 2,2'-dithiosalicylicacid (EBSA) in situ reaction by hydrothermal method. Complex 1 is a dinuclear structure and Cd²⁺ is five-coordinated in a distorted trigonal bipyramidal geometry. Complex 2 is a one-dimensional infinite linear chain and Ni²⁺ is six-coordinated to form a distorted octahedral geometry. Hydrogen bonding and π-π interactions are observed in these complexes.
- 2,2'-dithiosalicylicacid,
- in situ reaction,
- crystal structure
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