Citation: HAO Peng-Fei, YANG Jun-Juan, YANG Zhi, MA Xiao-Li, YANG Ying, LI Jia-Rong. Synthesis, Characterization and Thermal Property of the Aluminum Boroxine-linked Compound with N-aryl Substituted β-Diketiminato Ligand[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 729-734. doi: 10.14102/j.cnki.0254-5861.2011-0421 shu

Synthesis, Characterization and Thermal Property of the Aluminum Boroxine-linked Compound with N-aryl Substituted β-Diketiminato Ligand

HAO Peng-Fei ^a ,
YANG Jun-Juan ^a ,
YANG Zhi ^a,, ,
MA Xiao-Li ^a,, ,
YANG Ying ^b ,
LI Jia-Rong ^a

1.
a School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China;
2.
b School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China

Corresponding author: YANG Zhi, MA Xiao-Li,
Received Date: 18 June 2014
Available Online: 5 March 2015
Fund Project: This project was supported by the National Natural Science Foundation of China (No.21001016) (No.21001016) the Beijing Natural Science Foundation (No.2132044) (No.2132044)

The boroxine-linked organic aluminum compound LAl[OB(3-C₄H₃O)]₂(μ-O) was accomplished by reacting LAlH₂ {L=(Z)-4-[(2,6-diisopropylphenyl)amino]pent-3-en-2-ylidene-2,6-diisopropylaniline} with furan-3-ylboronic acid in good yield. The title compound belongs to the orthorhombic system, space group Pnma with a=10.9774(15), b=19.369(3), c=17.362(3) Å, V=3691.5(9) Å³, C₃₇H₄₇AlB₂N₂O₅, M_r=648.37, Z=4, D_c=1.167 Mg/m³, μ(MoKα)=0.097 mm^-1, F(000)=1384, S=1.000, the final R=0.0589 and wR=0.1445 for 9138 observed reflections (I>2σ(I)) and R=0.0683 and wR=0.1517 for all data. This compound is an unique example of a spiro-centered aluminum atom, showing the inorganic AlO₃B₂ ring fused to the organic C₃N₂ part. It was characterized by ¹H NMR, IR, elemental analysis, and single-crystal X-ray structural analysis. Furthermore, the compound was studied by TG analysis as well as DSC.
- β-diketiminato ligand,
- boroxine-linked,
- aluminum compound,
- thermal property
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