Citation: LV Yang-Yang, YE Li-Wang, XU Zhi-Huang, CAO You-Jie, SU Gen-Bo, ZHUANG Xin-Xin. Structure, Growth and Characterization of Ammonium 5-Sulfosalicylic Acid Monohydrate Crystal[J]. Chinese Journal of Structural Chemistry, ;2015, 34(3): 453-460. doi: 10.14102/j.cnki.0254-5861.2011-0386 shu

Structure, Growth and Characterization of Ammonium 5-Sulfosalicylic Acid Monohydrate Crystal

a.
a. Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
b.
b. University of Chinese Academy of Sciences, Beijing 100039, China

Received Date: 23 May 2014
Available Online: 16 December 2014
Fund Project:

Ammonium 5-sulfosalicylic acid monohydrate (NH₄·C₇H₅O₆S·H₂O, ASSA) was synthesized and optical grade crystal with dimensions of 45mm×20mm×18mm was obtained from aqueous solution by the cooling solution method. The crystal structure was confirmed by X-ray single-crystal diffraction method and the empirical composition is C₇H₁₁NO₇S with formula weight 253.23. The crystal belongs to monoclinic space group P2₁/c with a=11.884(9), b=7.306(5), c=12.152(9)Å, β=104.851(13)°, V=1019.8(13)Å³, Z=4, D_c=1.649 g/cm³, μ=0.340 mm^-1, F(000)=528, the final R=0.0307 and wR=0.0866 for 7494 observed reflections (I>2σ(I)). Elemental analysis, IR and ¹H-NMR spectrum were used to characterize the compound. Thermal analysis showed that one coordination water molecule was contained and dehydration temperature of ASSA crystal was 106℃. Optical transmission and fluorescence spectrum revealed that the ASSA crystal exhibited a strong absorption in ultraviolet region with the sharp absorption edge located at 340 nm and a significant blue fluorescent emission band at 442 nm.
- ammonium 5-sulfosalicylic acid monohydrate,
- crystal growth,
- crystal structure,
- fluorescence spectrum
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