Citation: XU Bo, LI Ling, LI Jie, LI Cun-Cheng. Crystal Structure and Luminescent Property of a Coordination Complex Constructed with Pyrazine and 1,4-Phenylenediacetic Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(12): 1826-1830. doi: 10.14102/j.cnki.0254-5861.2011-0378 shu

Crystal Structure and Luminescent Property of a Coordination Complex Constructed with Pyrazine and 1,4-Phenylenediacetic Acid

1.
Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong (University of Jinan), School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China

Corresponding author: XU Bo, LI Cun-Cheng,
Received Date: 19 May 2014
Available Online: 19 August 2014
Fund Project: Supported by the National Natural Science Foundation of China (No. 21301069) (No. 21301069)

A new coordination complex [Cd(pda)(pyz)(H₂O)₂]_n (1, H₂pda=1,4-phenylenediacetic acid, pyz=pyrazine) have been synthesized and structurally characterized. Crystal data for the title complex are as follows: orthorhombic system, space group Ccmb with a=11.5245(3) b=19.5069(5) c=11.4231(3)Ǻ, V=2568.00(12)Ǻ³, M_r=188.31, Z=16, F(000)=1480, D_c=1.948 g/cm³, μ(MoKα)=1.725 mm^-1, R=0.0195 and wR=0.0462 for 1357 observed reflections with I>2σ(I). In the title complex, the central Cd(Ⅱ) ion is located in a distorted octahedral coordination environment. Two Cd(Ⅱ) ions are bridged by two pda^2- ligands and one pyz ligand to form a bi-loop structure. Luminescent property of the complex has also been studied.
- coordination complex,
- crystal structure,
- luminescence,
- 1,4-phenylenediacetic acid
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