Citation: YANG Ying-Qun, TANG Si-Ping, ZENG Rong-Ying. Synthesis and Electrochemical, Fluorescent and Magnetic Properties of a New Cadmium(Ⅱ) Complex with 2-Benzoylbenzoic Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(12): 1849-1853. doi: 10.14102/j.cnki.0254-5861.2011-0371 shu

Synthesis and Electrochemical, Fluorescent and Magnetic Properties of a New Cadmium(Ⅱ) Complex with 2-Benzoylbenzoic Acid

1.
Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China

Corresponding author: YANG Ying-Qun, ZENG Rong-Ying,
Received Date: 15 May 2014
Available Online: 12 August 2014
Fund Project: Supported by the Scientific Research Fund of Hunan Provincial Education Department (No. 11C0186) (No. 11C0186)

A new cadmium(Ⅱ) complex Cd(OBBA)₂(2,2'-bipy)₂ with 2-benzoylbenzoic acid (HOBBA) and 2,2-bipyridine (2,2'-bipy) as ligands has been synthesized. Crystal data for the complex are as follows: monoclinic, space group P2₁/c with a=16.402(3), b=10.4191(18), c=23.395(4)Å, β=91.765(2)°, V=3996.2(12)Å³, D_c=1.455 g·cm^-3, Z=4, μ(MoKα)=0.603 mm^-1, F(000)=1784, the final R=0.0218 and wR=0.0558. In the electrode reaction, its electron transfer is quasi reversible and the electrode reaction corresponds to Cd(Ⅱ)/Cd(0). Under 618 nm radiation, the title complex shows a strong fluorescent band at around 326 nm. In addition, in the range of 2~300 K, this complex displays diamagnetic property.
- cadmium(Ⅱ) complex,
- 2-benzoylbenzoic acid,
- fluorescent and magnetic properties
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