Citation: GUO Ying-Chen, CHEN Shu-Yang, SUN Ru-Zhong, FENG Yu-Quan. Synthesis, Crystal Structure and Antibacterial Activity of Dibenzyl Dithiocarbamate Bismuth Complex[J]. Chinese Journal of Structural Chemistry, ;2014, 33(12): 1768-1772. doi: 10.14102/j.cnki.0254-5861.2011-0342 shu

Synthesis, Crystal Structure and Antibacterial Activity of Dibenzyl Dithiocarbamate Bismuth Complex

1.
College of Chemistry and Pharmay Engineering, Nanyang Normal University, Nanyang 473061, China

Corresponding author: GUO Ying-Chen,
Received Date: 17 April 2014
Available Online: 22 September 2014
Fund Project: Project supported by International Cooperation Project of the Science & Technology Agency of Henan Province (No. 134300510013) (No. 134300510013)

A new complex, {Bi(Ⅲ)[S₂CN(CH₂C₆H₅)₂]₃}₂·2CH₃CN, was synthesized and characterized by elemental analysis, IR, TG, ¹H NMR and X-ray single-crystal diffraction. The complex crystallizes in the triclinic system, space group P1, with a=12.705(6), b=13.430(6), c=15.489(12)Å, α=102.135(12), β=99.649(12), γ=111.521(9)°, Z=1, V=2315(2)Å³, D_c=1.531 g·cm^-3, F(000)=1068, μ=4.116 mm^-1, the final R=0.0559, wR=0.1069 and S=1.056. The coordinated geometry of Bi(Ⅲ) with six sulfur atoms from three ligands is a distorted pentagonal pyramidal configuration, and the structural system is formed by weak interactions of Bi…S between two molecules. The complex was valued for its antibacterial activity by agar-streak method. It was found that the complex is weakly active against three of the five tested bacterial organisms.
- bismuth(Ⅲ) dibenzyl dithiocarbamate,
- crystal structure,
- antibacterial activity
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