Citation: JIAO Xiao-Yan, HUANG Kun-Lin, ZHANG Ming-Xing, CHEN Xin. Structure and Photoluminescence of a 3D Coordination Polymer from Triazole and 2,6-Dimethylpyridine-3,5-dicarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1063-1068. doi: 10.14102/j.cnki.0254-5861.2011-0302 shu

Structure and Photoluminescence of a 3D Coordination Polymer from Triazole and 2,6-Dimethylpyridine-3,5-dicarboxylic Acid

a.
a. College of Science, Hebei North University, Zhangjiakou 075000, China;
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b. Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing 401331, China

Received Date: 28 March 2014
Available Online: 14 May 2015
Fund Project: Chongqing Normal University Scientific Research Foundation Project (2011XLS30) (KJ120663, KJ100602, KJ120632, KJ130638)Program for Innovation Team Building at Institutions of Higher Education in Chongqing (KJTD201309) (2011XLS30)

A new metal-organic coordination polymer [Zn₂(trz)₂(mpda)(H₂O)]_n (1, trz=1,2,4-triazole, H₂mpda=2,6-dimethylpyridine-3,5-dicarboxylic acid) was synthesized and characterized by single-crystal X-ray analyses. The crystal is of monoclinic system, space group P2₁/c, a=9.619(3), b=8.920(3), c=22.159(6)Å, β=96.897(4)°, V=1887.3(9)Å³, Z=4, M_r=478.04, D_c=1.682 Mg/m³, F(000)=960, the final R=0.0264 and wR=0.0870 (I>2σ(I)). Compound 1 consists of {[Zn₄(trz)₄]⁴⁺}_n layers, which are further connected by mpda^2- to complete a three-dimensional structure. The title compound exhibits luminescence at λ_max=415 nm upon excitation at 364 nm.
- crystal structure,
- photoluminescence,
- polymer,
- 2,6-dimethylpyridine-3,5-dicarboxylic acid
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