Citation: ZHANG Tian, XUE Li-Ping. Ionothermal Synthesis, Crystal Structure and Photocatalytic Property of a New Cobalt Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2015, 34(3): 417-422. doi: 10.14102/j.cnki.0254-5861.2011-0050 shu

Ionothermal Synthesis, Crystal Structure and Photocatalytic Property of a New Cobalt Coordination Polymer

ZHANG Tian ,
XUE Li-Ping ^,

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: XUE Li-Ping,
Received Date: 9 September 2014
Available Online: 17 November 2014
Fund Project: This work was supported by the Natural Science Foundation of Henan Province (132300410326) (132300410326)

The reaction of flexible bis(imidazole) ligand and 1,2-bis(imidazol-1'-yl)methane (bimm) with Co(Ⅱ) salt under ionothermal method resulted in the formation of a new coordination polymer {[Co(bimm)₃]·(PF₆)₂}_n (1). X-ray single-crystal diffraction determination reveals that 1 crystallizes in the triclinic P1 space group, with a=8.647(6), b=12.092(9), c=14.967(11)Å, α=88.912(8), β=81.199(8), γ=89.395(8)°, V=1546(2)Å³, Z=2, M_r=793.39, D_c=1.704 Mg/m³, μ=0.768 mm^-1, F(000)=798, the final R=0.0626 and wR=0.1634 for 4319 observed reflections with I>2σ(I). In compound 1, the Co(Ⅱ) ion is connected to another Co(Ⅱ) by two bimm ligands to form 1D double chains which are further linked by bimm ligands to form a 2D wavelike layer. Topologically, the structure of 1 represents a uninodal 2D 4-connected sql/Shubnikov tetragonal plane net. Moreover, thermogravimetric analyses and photocatalytic property for 1 have also been investigated.
- cobalt coordination polymer,
- crystal structure,
- photocatalytic property
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