Citation: Yu-Jie YIN, Wang-Jian FANG, Shu-Qin LIU, Jun CHEN, Jian-Jun ZHANG, Ai-Yun NI. A New Bio-metal-organic Framework: Synthesis, Crystal Structure and Selectively Sensing of Fe(Ⅲ) Ion in Aqueous Medium[J]. Chinese Journal of Structural Chemistry, ;2021, 40(11): 1456-1460. doi: 10.14102/j.cnki.0254–5861.2011–3180 shu

A New Bio-metal-organic Framework: Synthesis, Crystal Structure and Selectively Sensing of Fe(Ⅲ) Ion in Aqueous Medium

School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Corresponding author: Shu-Qin LIU, shuqinliu@163.com Jian-Jun ZHANG, zhangjj@dlut.edu.cn
Received Date: 16 March 2021
Accepted Date: 28 May 2021

Fund Project: the National Natural Science Foundation of China 21871038

Figures(5)

A new two-dimensional (2D) bio-metal-organic framework based on trinuclear cluster units, [Zn₃(adeninate)₂(CH₃COO)₄]∙DMF (Zn–A), was synthesized by the self-assembly of biomolecule adenines with zinc ions. Topological analysis reveals its 4⁴ connected layer structure. Remarkably, Zn–A bears high sensitivity and selectivity detection ability of iron ion with the limit of detection being 4.0 × 10^-6 mol/L.
- supramolecule,
- crystal structure,
- bio-metal-organic framework,
- Fe³⁺ ion,
- sensing
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沈阳化工大学材料科学与工程学院沈阳 110142