Citation: Ming CHEN, Jun-Mei ZHAO, Chuan-Fu SUN. High-volumetric-capacity WSe₂ Anode for Potassium-ion Batteries[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 926-932. doi: 10.14102/j.cnki.0254–5861.2011–3106 shu

High-volumetric-capacity WSe₂ Anode for Potassium-ion Batteries

Ming CHEN ^{a, b} ,
Jun-Mei ZHAO ^c ,
Chuan-Fu SUN ^{b, d,,}

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing 100190, China
d.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: Chuan-Fu SUN, cfsun@fjirsm.ac.cn
Received Date: 20 January 2021
Accepted Date: 21 February 2021

Fund Project: the National Natural Science Foundation of China 21771180the National Natural Science Foundation of China 21971239Natural Science Foundation of Fujian Province 2020J06032

Figures(4)

Exploring high-capacity electrode materials is critical for the development of K-ion batteries. In this work, we report a layered-structured tungsten selenide (WSe₂) anode, which not only delivers an ultrahigh volumetric capacity of 1772.8 Ah/L (or 188.4 mAh/g) at a current density of 5 mA/g but also exhibits good rate capability (72 mAh/g at 200 mA/g) and cycling stability (83.14% capacity retention over 100 cycles at 100 mA/g). We have also revealed the underlying reaction mechanism through ex situ X-ray powder diffraction. Furthermore, proof-of-concept full-cell batteries comprising of WSe₂ anodes and Prussian Blue cathodes are capable of delivering an energy density of 135.2 Wh/kg_{cathode+anode}. This work highlights the potential of WSe₂ as a promising high-volumetric-capacity anode material for rechargeable potassium-ion batteries.
- tungsten selenide,
- potassium-ion batteries,
- high volumetric capacity,
- conversion reaction
1. [1]
  Li, M.; Lu, J.; Chen, Z.; Amine, K. 30 years of lithium-ion batteries. Adv. Mater. 2018, 30, 1800561−24. doi: 10.1002/adma.201800561
2. [2]
  Armand, M.; Tarascon, J. M. Building better batteries. Nature 2008, 451, 652‒657. doi: 10.1038/451652a
3. [3]
  Goriparti, S.; Miele, E.; De Angelis, F.; Di Fabrizio, E.; Zaccaria, R. P.; Capiglia, C. Review on recent progress of nanostructured anode materials for Li-ion batteries. J. Power Sources 2014, 257, 421‒443. doi: 10.1016/j.jpowsour.2013.11.103
4. [4]
  Komaba, S.; Hasegawa, T.; Dahbi, M.; Kubota, K. Potassium intercalation into graphite to realize high-voltage/high-power potassium-ion batteries and potassium-ion capacitors. Electrochem. Commun. 2015, 60, 172‒175. doi: 10.1016/j.elecom.2015.09.002
5. [5]
  Wang, G.; Xiong, X. H.; Xie, D.; Lin, Z. H.; Zheng, J.; Zheng, F. H.; Li, Y. P.; Liu, Y. Z.; Yang, C. H.; Liu, M. L. Chemically activated hollow carbon nanospheres as a high-performance anode material for potassium ion batteries. J. Mater. Chem. A 2018, 6, 24317‒24323. doi: 10.1039/C8TA09751H
6. [6]
  Chu, S.; Cui, Y.; Liu, N. The path towards sustainable energy. Nat. Mater. 2016, 16, 16‒22.
7. [7]
  He, H.; Man, Y.; Yang, J.; Xie, J.; Xu, M. MoO₂ nanosheets embedded in amorphous carbon matrix for sodium-ion batteries. Roy. Soc. Open Sci. 2017, 4, 170892‒7. doi: 10.1098/rsos.170892
8. [8]
  Ren, X.; Zhao, Q.; McCulloch, W. D.; Wu, Y. MoS₂ as a long-life host material for potassium ion intercalation. Nano Research 2017, 10, 1313‒1321. doi: 10.1007/s12274-016-1419-9
9. [9]
  Zhang, R.; Bao, J.; Pan, Y.; Sun, C. F. Highly reversible potassium-ion intercalation in tungsten disulfide. Chem. Sci. 2019, 10, 2604‒2612. doi: 10.1039/C8SC04350G
10. [10]
  Yu, X. Y.; Hu, H.; Wang, Y.; Chen, H.; Lou, X. W. Ultrathin MoS₂ nanosheets supported on N-doped carbon nanoboxes with enhanced lithium storage and electrocatalytic properties. Angew. Chem. Int. Ed. 2015, 54, 7395‒7398. doi: 10.1002/anie.201502117
11. [11]
  Wu, R.; Wang, D. P.; Rui, X.; Liu, B.; Zhou, K.; Law, A. W.; Yan, Q.; Wei, J.; Chen, Z. In-situ formation of hollow hybrids composed of cobalt sulfides embedded within porous carbon polyhedra/carbon nanotubes for high-performance lithium-ion batteries. Adv. Mater. 2015, 27, 3038‒3044. doi: 10.1002/adma.201500783
12. [12]
  Jiao, X.; Liu, X.; Wang, B.; Wang, G.; Wang, X.; Wang, H. A controllable strategy for the self-assembly of WM nanocrystals/nitrogen-doped porous carbon superstructures (M = O, C, P, S, and Se) for sodium and potassium storage. J. Mater. Chem. A 2020, 8, 2047‒2065. doi: 10.1039/C9TA11312F
13. [13]
  Zhang, R.; Huang, J.; Deng, W.; Bao, J.; Pan, Y.; Huang, S.; Sun, C. F. Safe, low-cost, fast-kinetics and low-strain inorganic-open-framework anode for potassium-ion batteries. Angew. Chem. Int. Ed. 2019, 58, 16474‒16479. doi: 10.1002/anie.201909202
14. [14]
  Mao, M.; Cui, C.; Wu, M.; Zhang, M.; Gao, T.; Fan, X.; Chen, J.; Wang, T.; Ma, J.; Wang, C. Flexible ReS₂ nanosheets/N-doped carbon nanofibers-based paper as a universal anode for alkali (Li, Na, K) ion battery. Nano Energy 2018, 45, 346‒352. doi: 10.1016/j.nanoen.2018.01.001
15. [15]
  Xu, B.; Ma, X.; Tian, J.; Zhao, F.; Liu, Y.; Wang, B.; Yang, H.; Xia, Y. Layer-structured NbSe₂ anode material for sodium-ion and potassium-ion batteries. Ionics 2019, 25, 4171‒4177. doi: 10.1007/s11581-019-03005-5
16. [16]
  Wu, M.; Yang, J.; Ng, D. H. L.; Ma, J. Rhenium diselenide anchored on reduced graphene oxide as anode with cyclic stability for potassium-ion battery. Phys. Status Solidi Rapid Res. Lett. 2019, 13, 1900329‒7. doi: 10.1002/pssr.201900329
17. [17]
  Wang, W.; Jiang, B.; Qian, C.; Lv, F.; Feng, J.; Zhou, J.; Wang, K.; Yang, C.; Yang, Y.; Guo, S. Pistachio-shuck-like MoSe₂/C core/shell nanostructures for high-performance potassium-ion storage. Adv. Mater. 2018, 30, 1801812‒7. doi: 10.1002/adma.201801812
18. [18]
  Sun, C. F.; Hu, J.; Wang, P.; Cheng, X. Y.; Lee, S. B.; Wang, Y. Li₃PO₄ matrix enables a long cycle life and high energy efficiency bismuth-based battery. Nano Lett. 2016, 16, 5875‒5882. doi: 10.1021/acs.nanolett.6b02720
19. [19]
  Sun, C. F.; Zhu, H.; Okada, M.; Gaskell, K.; Inoue, Y.; Hu, L.; Wang, Y. Interfacial oxygen stabilizes composite silicon anodes. Nano Lett. 2015, 15, 703‒708. doi: 10.1021/nl504242k
20. [20]
  Jian, Z.; Luo, W.; Ji, X. Carbon electrodes for K-ion batteries. J. Am. Chem. Soc. 2015, 137, 11566‒11569. doi: 10.1021/jacs.5b06809
21. [21]
  Fan, H. N.; Wang, X. Y.; Yu, H. B.; Gu, Q. F.; Chen, S. L.; Liu, Z.; Chen, X. H.; Luo, W. B.; Liu, H. K. Enhanced potassium ion battery by inducing interlayer anionic ligands in MoS_1.5Se_0.5 nanosheets with exploration of the mechanism. Adv. Energy Mater. 2020, 10, 1904162‒9. doi: 10.1002/aenm.201904162
22. [22]
  Jian, Z.; Xing, Z.; Bommier, C.; Li, Z.; Ji, X. Hard carbon microspheres: potassium-ion anode versus sodium-ion anode. Adv. Energy Mater. 2016, 6, 1501874‒5. doi: 10.1002/aenm.201501874
23. [23]
  Hu, X.; Liu, Y.; Chen, J.; Yi, L.; Zhan, H.; Wen, Z. Fast redox kinetics in Bi-heteroatom doped 3D porous carbon nanosheets for high-performance hybrid potassium-ion battery capacitors. Adv. Energy Mater. 2019, 9, 1901533‒10. doi: 10.1002/aenm.201901533
24. [24]
  Alvin, S.; Cahyadi, H. S.; Hwang, J.; Chang, W.; Kwak, S. K.; Kim, J. Revealing the intercalation mechanisms of lithium, sodium, and potassium in hard carbon. Adv. Energy Mater. 2020, 10, 2000283‒16. doi: 10.1002/aenm.202000283
25. [25]
  Fan, L.; Ma, R.; Wang, J.; Yang, H.; Lu, B. An ultrafast and highly stable potassium-organic battery. Adv. Mater. 2018, 30, 1805486‒8. doi: 10.1002/adma.201805486
26. [26]
  Fan, L.; Ma, R.; Zhang, Q.; Jia, X.; Lu, B. Graphite anode for a potassium-ion battery with unprecedented performance. Angew. Chem. Int. Ed. 2019, 58, 10500‒10505. doi: 10.1002/anie.201904258
27. [27]
  Han, J.; Niu, Y.; Bao, S. J.; Yu, Y. N.; Lu, S. Y.; Xu, M. Nanocubic KTi₂(PO₄)₃ electrodes for potassium-ion batteries. Chem. Commun. 2016, 52, 11661‒11664. doi: 10.1039/C6CC06177J
28. [28]
  Kishore, B.; Venkatesh, G.; Munichandraiah, N. K₂Ti₄O₉: a promising anode material for potassium ion batteries. J. Electrochem. Soc. 2016, 163, A2551‒A2554. doi: 10.1149/2.0421613jes
29. [29]
  Lakshmi, V.; Chen, Y.; Mikhaylov, A. A.; Medvedev, A. G.; Sultana, I.; Rahman, M. M.; Lev, O.; Prikhodchenko, P. V.; Glushenkov, A. M. Nanocrystalline SnS₂ coated onto reduced graphene oxide: demonstrating the feasibility of a non-graphitic anode with sulfide chemistry for potassium-ion batteries. Chem. Commun. 2017, 53, 8272‒8275. doi: 10.1039/C7CC03998K
30. [30]
  Lei, K.; Li, F.; Mu, C.; Wang, J.; Zhao, Q.; Chen, C.; Chen, J. High K-storage performance based on the synergy of dipotassium terephthalate and ether-based electrolytes. Energy Environ. Sci. 2017, 10, 552‒557. doi: 10.1039/C6EE03185D
31. [31]
  Sultana, I.; Rahman, M. M.; Ramireddy, T.; Chen, Y.; Glushenkov, A. M. High capacity potassium-ion battery anodes based on black phosphorus. J. Mater. Chem. A 2017, 5, 23506‒23512. doi: 10.1039/C7TA02483E
32. [32]
  Sultana, I.; Ramireddy, T.; Rahman, M. M.; Chen, Y.; Glushenkov, A. M. Tin-based composite anodes for potassium-ion batteries. Chem. Commun. 2016, 52, 9279‒9282. doi: 10.1039/C6CC03649J
33. [33]
  Wang, L.; Zou, J.; Chen, S.; Zhou, G.; Bai, J.; Gao, P.; Wang, Y.; Yu, X.; Li, J.; Hu, Y. S.; Li, H. TiS₂ as a high performance potassium ion battery cathode in ether-based electrolyte. Energy Storage Mater. 2018, 12, 216‒222. doi: 10.1016/j.ensm.2017.12.018
34. [34]
  Zhou, J.; Wang, L.; Yang, M.; Wu, J.; Chen, F.; Huang, W.; Han, N.; Ye, H.; Zhao, F.; Li, Y.; Li, Y. Hierarchical VS₂ nanosheet assemblies: a universal host material for the reversible storage of alkali metal ions. Adv. Mater. 2017, 29, 1702061‒8. doi: 10.1002/adma.201702061
35. [35]
  Xue, L.; Li, Y.; Gao, H.; Zhou, W.; Lu, X.; Kaveevivitchai, W.; Manthiram, A.; Goodenough, J. B. Low-cost high-energy potassium cathode. J. Am. Chem. Soc. 2017, 139, 2164‒2167. doi: 10.1021/jacs.6b12598
1. [1]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
2. [2]
  Zhuangzhuang Zhang , Yaru Qiao , Jun Zhao , Dai-Huo Liu , Mengmin Jia , Hongwei Tang , Liang Wang , Dongmei Dai , Bao Li . Fluorine-doped K_0.39Mn_0.77Ni_0.23O_1.9F_0.1 microspheres with highly reversible oxygen redox reaction for potassium-ion battery cathode. Chinese Chemical Letters, 2025, 36(3): 109907-. doi: 10.1016/j.cclet.2024.109907
3. [3]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
4. [4]
  Jun-Ming Cao , Kai-Yang Zhang , Jia-Lin Yang , Zhen-Yi Gu , Xing-Long Wu . Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives. Chinese Chemical Letters, 2024, 35(4): 109304-. doi: 10.1016/j.cclet.2023.109304
5. [5]
  Ajay Piriya Vijaya Kumar Saroja , Yuhan Wu , Yang Xu . Improving the electrocatalysts for conversion-type anodes of alkali-ion batteries. Chinese Journal of Structural Chemistry, 2025, 44(1): 100408-100408. doi: 10.1016/j.cjsc.2024.100408
6. [6]
  Weidan Meng , Yanbo Zhou , Yi Zhou . Green innovation unleashed: Harnessing tungsten-based nanomaterials for catalyzing solar-driven carbon dioxide conversion. Chinese Chemical Letters, 2025, 36(2): 109961-. doi: 10.1016/j.cclet.2024.109961
7. [7]
  Yang Li , Xiaoxu Liu , Tianyi Ji , Man Zhang , Xueru Yan , Mengjie Yao , Dawei Sheng , Shaodong Li , Peipei Ren , Zexiang Shen . Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109551-. doi: 10.1016/j.cclet.2024.109551
8. [8]
  Zhao Li , Huimin Yang , Wenjing Cheng , Lin Tian . Recent progress of in situ/operando characterization techniques for electrocatalytic energy conversion reaction. Chinese Chemical Letters, 2024, 35(9): 109237-. doi: 10.1016/j.cclet.2023.109237
9. [9]
  Xuan Liu , Qing Li . Tailoring interatomic active sites for highly selective electrocatalytic biomass conversion reaction. Chinese Chemical Letters, 2025, 36(4): 110670-. doi: 10.1016/j.cclet.2024.110670
10. [10]
  Tao LIU , Yuting TIAN , Ke GAO , Xuwei HAN , Ru'nan MIN , Wenjing ZHAO , Xueyi SUN , Caixia YIN . A photothermal agent with high photothermal conversion efficiency and high stability for tumor therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1622-1632. doi: 10.11862/CJIC.20240107
11. [11]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
12. [12]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
13. [13]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
14. [14]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
15. [15]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
16. [16]
  Fan Wu , Shaoyang Wu , Xin Ye , Yurong Ren , Peng Wei . Research progress of high-entropy cathode materials for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(4): 109851-. doi: 10.1016/j.cclet.2024.109851
17. [17]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
18. [18]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
19. [19]
  Ya Song , Mingxia Zhou , Zhu Chen , Huali Nie , Jiao-Jing Shao , Guangmin Zhou . Integrated interconnected porous and lamellar structures realized fast ion/electron conductivity in high-performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(6): 109200-. doi: 10.1016/j.cclet.2023.109200
20. [20]
  Bin Feng , Tao Long , Ruotong Li , Yuan-Li Ding . Rationally constructing metallic Sn-ZnO heterostructure via in-situ Mn doping for high-rate Na-ion batteries. Chinese Chemical Letters, 2025, 36(2): 110273-. doi: 10.1016/j.cclet.2024.110273

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(375)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

High-volumetric-capacity WSe2 Anode for Potassium-ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

High-volumetric-capacity WSe₂ Anode for Potassium-ion Batteries