Citation: De-Yi ZHANG, Guo-Hui KANG, Rong LIANG, Shao-Bin MIAO, Chun-Ying XU, Bao-Ming JI. A New 3D Supramolecular Complex (Dimethylammonium 4, 4΄-([2, 2΄-Bipyrimidine]-5, 5΄-diyl)bis(2-hydroxybenzoate) Dihydrate): Synthesis, Structure =and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 955-961. doi: 10.14102/j.cnki.0254–5861.2011–3058 shu

A New 3D Supramolecular Complex (Dimethylammonium 4, 4΄-([2, 2΄-Bipyrimidine]-5, 5΄-diyl)bis(2-hydroxybenzoate) Dihydrate): Synthesis, Structure =and Luminescent Property

De-Yi ZHANG ^{a, b} ,
Guo-Hui KANG ^b ,
Rong LIANG ^{b, c} ,
Shao-Bin MIAO ^b ,
Chun-Ying XU ^b ,
Bao-Ming JI ^{a, b, c,,}

a.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
b.
Henan Key Laboratory of Function-oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471934, China
c.
College of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China

Corresponding author: Bao-Ming JI, lyhxxjbm@126.com
Received Date: 7 December 2020
Accepted Date: 4 February 2021

Fund Project: the National Natural Science Foundation of China 21372112

Figures(7)

A new 3D supramolecular complex, namely dimethylammonium 4, 4΄-([2, 2΄-bipyrimidine]-5, 5΄-diyl)bis(2-hydroxybenzoate) dihydrate, has been synthesized by the reaction of 4, 4΄-([2, 2΄-bipyrimidine]-5, 5΄-diyl)bis(2-hydroxybenzoic acid) with aqueous dimethylamine solution and characterized by single-crystal X-ray diffraction, ¹H NMR spectroscopy and elemental analysis. It belongs to triclinic system, space groupP\begin{document}$ \overline 1 $\end{document} with a = 6.5539(4), b = 9.4977(6), c = 12.1407(8) Å, α = 72.299(6), β = 89.160(5), γ = 70.797(8)°, V = 676.52(8) Å³, Z = 1, M_r = 556.57, µ = 0.103 mm^-1, D_c = 1.366 g/cm³, F(000) = 294, the final R =0.0828 and wR = 0.2083 for 1934 observed reflections with I > 2σ(I). The 4, 4΄-([2, 2΄-bipyrimidine]-5, 5΄-diyl)bis(2-hydroxybenzoic acid) dianion, dimethylammonium cation, and water molecule are interconnected by O−H∙∙∙O, N−H∙∙∙N, and N−H∙∙∙O hydrogen bonds, forming a two-dimensional (2D) layer. Two adjacent 2D layers are further stacked into a three-dimensional supramolecular structure through O−H∙∙∙O hydrogen bonds. In addition, the luminescent property of this supramolecular complex has also been investigated.
- 4, 4΄-([2, 2΄-bipyrimidine]-5, 5΄-diyl)bis(2-hydroxybenzoic acid),
- dimethylammonium,
- crystal structure
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