Citation: Wei LI, Chang-Hong LI, Shui-Qi ZHOU, Yu-Lin LI, Yun-Fei KUANG. Synthesis, Crystal Structure and Characterization of a New Manganese(II) Complex with o-Benzoylbenzoic Acid[J]. Chinese Journal of Structural Chemistry, ;2021, 40(5): 631-636. doi: 10.14102/j.cnki.0254–5861.2011–3057 shu

Synthesis, Crystal Structure and Characterization of a New Manganese(II) Complex with o-Benzoylbenzoic Acid

a.
School of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
b.
School of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China
c.
Zhejiang Center Good-testing Service Co. Ltd. Zhejiang 321025, China

Corresponding author: Wei LI, li_weihnxy@163.com Chang-Hong LI, lichanghong4444@126.com
Received Date: 7 December 2020
Accepted Date: 20 January 2021

Fund Project: the Natural Science Foundation of Hunan Province 2019JJ60021Industry and Research Key Project of Hengyang City 2019jhzx1093

Figures(5)

A new manganese(II) complex [Mn(C₁₄H₉O₃)₂(C₁₂H₈N₂)₂]·4H₂O (1) was synthesized with o-ben- zoylbenzoic acid, manganese sulfate and 1, 10-phenanthroline (phen) in the mixture of acetonitrile and water solvent. It crystallizes (C₅₂H₄₂MnN₄O₁₀, M_r = 937.83) in monoclinic, space group P2₁/n with a = 13.3528(5), b = 17.6963(6), c = 19.7889(7) Å, β = 109.647(4)º, V = 4403.8(3) Å³, D_c = 1.415 g/cm³, Z = 4, F(000) = 1948, μ(MoKα) = 0.368 mm^-1, R = 0.0404 and wR = 0.0956. The crystal structure shows that the manganese ion is coordinated with two oxygen atoms from two o-benzoylbenzoic acid molecules and four nitrogen atoms from two phen molecules, forming a distorted octahedral coordination geometry. The TG, spectrum analysis and magnetic properties of 1 were studied.
- manganese(II) complex,
- spectrum analysis,
- thermal stability,
- magnetic property
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