Citation: Fang-Yu YUAN, Yi-Zhi HUANG, Hao ZHANG, An-Yi ZHOU, Wen-Dan CHENG, Chen-Sheng LIN. Synthesis and Characterization of a New Quaternary Selenide New Quaternary Selenide Ba₄Sn₃GeSe₉ Containing [SnGeSe₅]^4- and [Sn₂Se₄]^4- Units[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 962-966. doi: 10.14102/j.cnki.0254–5861.2011–3048 shu

Synthesis and Characterization of a New Quaternary Selenide New Quaternary Selenide Ba₄Sn₃GeSe₉ Containing [SnGeSe₅]^4- and [Sn₂Se₄]^4- Units

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

Corresponding author: Chen-Sheng LIN, cslin@fjirsm.ac.cn
Received Date: 25 November 2020
Accepted Date: 17 December 2020

Fund Project: the National Natural Science Foundation of China 21703248the National Key Research and Development Program of China 2017YFA0700103the National Key Research and Development Program of China 2018YFA0704502the Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000

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A new quaternary selenide Ba₄Sn₃GeSe₉ was synthesized by high temperature solid state reaction method and fully characterized by elemental analysis, UV-vis spectrum, and single-crystal X-ray diffraction. The title compound crystallizes in the orthorhombic space group Pnma with a = 12.463(3), b = 9.308(2) and c = 17.892(5) Å. Ba₄Sn₃GeSe₉ can be characterized by a zero-dimensional compound composed by special [GeSnSe₅]^4- units, [Sn₂Se₄]^4- units and the adjacent cations Ba²⁺ ions. The [GeSnSe₅]^4- unit is composed of a SnSe₃ trigonal pyramid formed by divalent Sn²⁺ and edge-sharing with a GeSe₄ tetrahedron, and the [Sn₂Se₄]^4- unit is composed of two SnSe₃ trigonal pyramids. Ba₄Sn₃GeSe₉ is an indirect semiconductor with a band gap of 1.21 eV.
- quaternary selenide,
- zero-dimensional structure,
- [GeSnSe₅]^4-unit,
- indirect band gap
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Characterization of a New Quaternary Selenide New Quaternary Selenide Ba4Sn3GeSe9 Containing [SnGeSe5]4- and [Sn2Se4]4- Units

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Characterization of a New Quaternary Selenide New Quaternary Selenide Ba₄Sn₃GeSe₉ Containing [SnGeSe₅]^4- and [Sn₂Se₄]^4- Units