Citation: Sheng-Ze YUAN, Kui XIE. Enhanced Oxidative Coupling of Methane with Oxygen Permeation Membrane[J]. Chinese Journal of Structural Chemistry, ;2020, 39(12): 2115-2122. doi: 10.14102/j.cnki.0254–5861.2011–3025 shu

Enhanced Oxidative Coupling of Methane with Oxygen Permeation Membrane

Sheng-Ze YUAN ^{a, b} ,
Kui XIE ^{a, b,,}

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
Key Laboratory of Design & Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Kui XIE, kxie@fjirsm.ac.cn
Received Date: 3 November 2020
Accepted Date: 13 November 2020

Fund Project: the National Key Research and Development Program of China 2017YFA0700102National Natural Science Foundation of China 91845202Dalian National Laboratory for Clean Energy DNL180404Strategic Priority Research Program of Chinese Academy of Sciences XDB2000000

Figures(5)

Oxidative coupling of methane to ethylene is of high importance to the future of light olefin industry. However, the carbon atom efficiency is normally below 50% in gas phase reaction which is limited to the overoxidation of methane to carbon dioxide with oxidants. Here we present an alternative approach of electrochemical oxidation of methane in an oxygen permeation membrane reactor and show the highest conversion of methane and C₂ selectivity of 28% and 40.2% at 1150 ℃, respectively. We prepare the 100-μm-thick perovskite (La_0.8Sr_0.2)_1-xCr_0.5Fe_0.5O_3-δ (LSCrF) dense membrane supported on the 500-μm-thick porous (La_0.8Sr_0.2)_1-xCr_0.5Fe_0.5O_3-δ (LSCrF–Fe) (x = 0, 0.02, 0.05 and 0.10) scaffolds while the excess of Fe would be exsolved on porous skeleton to create metal-oxide interfaces toward methane oxidation. The metal-oxide interfaces not only facilitate the activation of C–H bond in methane but also enhance the coking resistance.
- oxidative coupling of methane,
- oxygen permeation membrane,
- nanoparticles,
- metal-oxide interfaces
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