Citation: Jin-Feng CHU, Shu-Ying WANG, Ming-Yu ZHANG, Qi-Xin XU, You-Qing WANG. Syntheses, Crystal Structures, Non-covalent Interactions and Properties of a Nickel(II) Complex Monomer and Its Dimer[J]. Chinese Journal of Structural Chemistry, ;2020, 39(10): 1877-1884. doi: 10.14102/j.cnki.0254–5861.2011–2815 shu

Syntheses, Crystal Structures, Non-covalent Interactions and Properties of a Nickel(II) Complex Monomer and Its Dimer

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Jin-Feng CHU, chujf@mail.buct.edu.cn
Received Date: 18 March 2020
Accepted Date: 27 May 2020

Fund Project: the Fundamental Research Funds for the Central Universities XK1802-6the Fundamental Research Funds for the Central Universities XK1803-05the Fundamental Research Funds for the Central Universities XK1902the Fundamental Research Funds for the Central Universities 12060093063

Figures(7)

A pair of nickel(II) complexes monomer and dimer, namely [NiCl₂(L)] (1) and [Ni₂Cl₂(L)₂(μ-Cl)₂] (2) (L = 2-morpholine-4-yl-4, 6-di-pyrazol-1-yl-1, 3, 5-triazine), were synthesized by using L to react with NiCl₂·2H₂O at 35 and 65 ℃, respectively. X-ray crystal structures of complexes 1 and 2 were determined. Complex 1 is mononuclear and its nickel(II) center resides in a distorted square-pyramidal environment with a NiN₃Cl₂ donor set, but complex 2 is binuclear and its nickel(II) center shows a distorted octahedral geometry with a NiN₃Cl₃ donor set. In complex 2, two adjacent nickel(II) centers are connected by two bridging chloride anions. Complexes 1 and 2 form different three-dimensional supramolecular structures through non-covalent interactions such as π-π stacking interactions, anion-π interactions and weak hydrogen bonds. Both complexes were further characterized by thermal gravimetric analyses and spectroscopic methods.
- nickel complex,
- monomer,
- dimer,
- crystal structure,
- spectroscopic properties
1. [1]
  Wang, A. N.; Fan, R. Q.; Dong, Y. W.; Chen, W.; Song, Y. W.; Wang, P.; Hao, S.; Liu, Z. G.; Yang, Y. L. (E)-4-Methyl-N-((quinolin-2- yl)ethylidene)aniline as ligand for IIB supramolecular complexes: synthesis, structure, aggregation-induced emission enhancement and application in PMMA-doped hybrid material. Dalton Trans. 2017, 46, 71–85. doi: 10.1039/C6DT03853K
2. [2]
  Strelnik, I. D.; Musina, E. I.; Karasik, A. A.; Sizov, V. V.; Grachova, E. V.; Gurzhiy, V. V.; Melnikov, A. S.; Kolesnikov, I. E. Binuclear gold(I) phosphine alkynyl complexes templated on a flexible cyclic phosphine ligand: synthesis and some features of solid-state luminescence. Inorg. Chem. 2020, 59, 244–253. doi: 10.1021/acs.inorgchem.9b02091
3. [3]
  Yang, L. G.; Wang, X.; Zhang, Y. H.; Li, Z. M.; Song, H. X.; Niu, Y. S.; Tao, Z.; Liu, Q. Y.; Xiao, X. Structure and electrochemical studies on the complexation of hexacyclohexanocucurbit[6]uril with lead ion. Polyhedron 2018, 142, 58–62. doi: 10.1016/j.poly.2017.12.035
4. [4]
  Zhang, Y.; Ali, B.; Wu, J. F.; Guo, M.; Yu, Y.; Liu, Z. L.; Tang, J. K. Construction of metallosupramolecular coordination complexes: from lanthanide helicates to octahedral cages showing single-molecule magnet behavior. Inorg. Chem. 2019, 58, 3167–3174. doi: 10.1021/acs.inorgchem.8b03249
5. [5]
  Nakada, A.; Koike, K.; Nakashima, T.; Morimoto, T.; Ishitani, O. Photocatalytic CO₂ reduction to formic acid using a Ru(II)-Re(I) supramolecular complex in an aqueous solution. Inorg. Chem. 2015, 54, 1800–1807. doi: 10.1021/ic502707t
6. [6]
  Wenz, K. M.; Leonhardt-Lutterbeck, G.; Breit, B. Inducing axial chirality in a supramolecular catalyst. Angew. Chem. Int. Ed. 2018, 57, 5100–5104. doi: 10.1002/anie.201801048
7. [7]
  Chen, L. D.; Zhou, L. X.; Zheng, Y. Q.; Zhu, H. L. Two new Ag(I) supramolecular complexes based on melamine: synthesis, structures and photocatalytic activity under visible light irradiation. Polyhedron 2017, 126, 150–158. doi: 10.1016/j.poly.2017.01.031
8. [8]
  Freire, C.; Nunes, M.; Pereira, C.; Fernandes, D. M.; Peixoto, A. F.; Rocha, M. Metallo(salen) complexes as versatile building blocks for the fabrication of molecular materials and devices with tuned properties. Coord. Chem. Rev. 2019, 394, 104–134. doi: 10.1016/j.ccr.2019.05.014
9. [9]
  Hu, M. L.; Morsali, A.; Aboutorabi, L. Lead(II) carboxylate supramolecular compounds: coordination modes, structures and nano-structure aspects. Coord. Chem. Rev. 2011, 255, 2821–2859. doi: 10.1016/j.ccr.2011.05.019
10. [10]
  Walczak, A.; Stefankiewicz, A. R. pH-Induced linkage isomerism of Pd(II) complexes: a pathway to air- and water-stable suzuki-miyaura-reaction catalysts. Inorg. Chem. 2018, 57, 471–477. doi: 10.1021/acs.inorgchem.7b02711
11. [11]
  Hema, M. K.; Karthik, C. S.; Pampa, K. J.; Manukumar, H. M.; Mallu, P.; Warad, I.; Lokanath, N. K. Solvent induced 4, 4, 4-trifluoro-1-(2-naphthyl)-1, 3-butanedione Cu(II) complexes: synthesis, structure, DFT calculation and biocidal activity. Polyhedron 2019, 168, 127–137. doi: 10.1016/j.poly.2019.04.028
12. [12]
  Jiang, P.; Peng, F.; Chen, Y. M. Temperature-induced single-crystal-to-single-crystal transformation of a binuclear Mn(II) complex into a 1D chain polymer. RSC Adv. 2016, 6, 89192–89197. doi: 10.1039/C6RA14364D
13. [13]
  Takjoo, R.; Mashmoul Moghadam, S. M.; Amiri Rudbari, H.; Bruno, G. Synthesis and X-ray crystal structures of some isothiosemicarbazone complexes. Transit. Met. Chem. 2019, 44, 525–534. doi: 10.1007/s11243-019-00310-w
14. [14]
  Takai, A.; Chkounda, M.; Eggenspiller, A.; Gros, C. P.; Lachkar, M.; Barbe, J. M.; Fukuzumi, S. Efficient photoinduced electron transfer in a porphyrin tripod-fullerene supramolecular complex via π-π interactions in nonpolar media. J. Am. Chem. Soc. 2010, 132, 4477–4489. doi: 10.1021/ja100192x
15. [15]
  Parra-Munoz, N.; Hidalgo, P. I.; Ripoll, G.; Belmar, J.; Pasan, J.; Jimenez, C. A. Influence of counterions on the supramolecular frameworks of isoquinoline-based silver(I) complexes. CrystEngComm. 2020, 22, 95–104. doi: 10.1039/C9CE01411J
16. [16]
  Mohana, M.; Muthiah, P. T.; McMillen, C. D. Supramolecular architectures in two 1: 1 cocrystals of 5-fluorouracil with 5-bromothiophene-2-carboxylic acid and thiophene-2-carboxylic acid. Acta Cryst. 2017, C73, 481–485.
17. [17]
  Nowroozi, A.; Ebrahimi, A.; Rezvani, R. O. Mutual effects of the cation-π, anion-π and intramolecular hydrogen bond in the various complexes of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene with some cations (Li⁺, Na⁺, K⁺, Mg²⁺, Ca²⁺) and anions (F^–, Cl^–, Br^–). Struct. Chem. 2018, 29, 129–137. doi: 10.1007/s11224-017-1010-3
18. [18]
  Xiao, G. B.; Fang, Z. H.; Yao, X. Q. A new cadmium(II) coordination polymer extended through hydrogen bonds and π-π stacking interactions: synthesis and photoluminescence property. Chin. J. Struct. Chem. 2018, 37, 1987–1993.
19. [19]
  Tom, L.; Aiswarya, N.; Sreejith, S. S.; Kurup, M. R. P. Self-organized three dimensional architectures based on non-covalent interactions in square planar Cu(II) thiosemicarbazone: solvent mediated crystallization and EPR based correlation study. Inorg. Chim. Acta 2018, 473, 223–235. doi: 10.1016/j.ica.2018.01.005
20. [20]
  Wan, Q. Y.; Xiao, X. S.; To, W. P.; Lu, W.; Chen, Y.; Low, K. H.; Che, C. M. Counteranion- and solvent-mediated chirality transfer in the supramolecular polymerization of luminescent platinum(II) complexes. Angew. Chem. Int. Ed. 2018, 57, 17189–17193. doi: 10.1002/anie.201811943
21. [21]
  Zhou, Q. K.; Wang, L.; Liu, D. Construction of a three-dimensional supramolecular framework based on an anionic cadmium(II) coordination network and protonated dipyridine organic cations. Acta Cryst. 2018, C74, 889–893.
22. [22]
  Engeldinger, E.; Armspach, D.; Matt, D.; Jones, P. G.; Welter, R. A cyclodextrin diphosphane as a first and second coordination sphere cavitand: evidence for weak C–H···Cl–M hydrogen bonds within metal-capped cavities. Angew. Chem. Int. Ed. 2002, 41, 2593–2596. doi: 10.1002/1521-3773(20020715)41:14<2593::AID-ANIE2593>3.0.CO;2-M
23. [23]
  Frontera, A.; Gamez, P.; Mascal, M.; Mooibroek, T. J.; Reedijk, J. Putting anion-π interactions into perspective. Angew. Chem. Int. Ed. 2011, 50, 9564–9583. doi: 10.1002/anie.201100208
24. [24]
  Bettencourt-Dias, A.; Beeler, R. M.; Zimmerman, J. R. Anion-π and H-bonding interactions supporting encapsulation of [Ln(NO₃)_6/5]^3–^/2– (Ln = Nd, Er) with a triazine-based ligand. J. Am. Chem. Soc. 2019, 141, 15102–15110. doi: 10.1021/jacs.9b05566
25. [25]
  Schottel, B. L.; Chifotides, H. T.; Dunbar, K. R. Anion-π interactions. Chem. Soc. Rev. 2008, 37, 68–83. doi: 10.1039/B614208G
26. [26]
  Chen, W.; Chu, J. F.; Wang, Y. Q. Synthesis, characterization and preliminary reactivity behaviors with transitional metals of a new polydentate N-donor ligand. J. Mol. Struct. 2014, 1068, 237–244. doi: 10.1016/j.molstruc.2014.04.031
27. [27]
  Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. OLEX₂: a complete structure solution, refinement and analysis program. J. Appl. Cryst. 2009, 42, 339–341. doi: 10.1107/S0021889808042726
28. [28]
  Sheldrick, G. M. A short history of SHELX. Acta Cryst. 2008, A64, 112–122.
29. [29]
  Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures. University of Göttingen. Göttingen, Germany 1997.
30. [30]
  Yun, J. X.; Hu, Z. L.; Li, Y. M.; Jin, J.; Chen, C.; Yan, X.; Liu, Y. H.; Ding, Y.; Chi, Y. X.; Niu, S. Y. Synthesis, structure and photoelectric property of a series of Ni(Ⅱ) complexes constructed through aromatic carboxylic ligands. Chem. J. Chin. Univ. 2018, 39, 2161–2169.
31. [31]
  Rodríguez, A.; García-Vázquez, J. A.; Romero, J.; Sousa-Pedrares, A.; Sousa, A.; Castro, J. Electrochemical synthesis and characterization of cobalt(II), cobalt(III), and nickel(II) complexes with pyrimidine-2-thionato ligands. Z. Anorg. Allg. Chem. 2007, 633, 763–770. doi: 10.1002/zaac.200600387
32. [32]
  Vallarino, L. M.; Goedken, V. L.; Quagliano, J. V. Donor properties of positively charged ligands. Metal complexes of the N-chloromethyl-dabconium ligand. Inorg. Chem. 1973, 12, 102–107. doi: 10.1021/ic50119a026
33. [33]
  Ainscough, E. W.; Brodie, A. M.; Depree, C. V.; Otter, C. A. Divalent cobalt, nickel and zinc halide complexes with multimodal ligands based on the cyclotriphosphazene platform: a structural study. Polyhedron 2006, 25, 2341–2352 doi: 10.1016/j.poly.2006.02.001
34. [34]
  Beattie, J. W.; White, D. S.; Bheemaraju, A.; Martin, P. D.; Groysman, S. Recyclable chemosensor for oxalate based on bimetallic complexes of a dinucleating bis(iminopyridine) ligand. Dalton Trans. 2014, 43, 7979–7986. doi: 10.1039/C4DT00577E
35. [35]
  Hamaguchi, T.; Ando, I. Synthesis and characterisation of a new six-coordinated thermochromic Ni complex. Inorg. Chim. Acta 2015, 427, 144–149. doi: 10.1016/j.ica.2014.12.013
36. [36]
  Pitchaimani, J.; Karthikeyan, S.; Lakshminarasimhan, N.; Anthony, S. P.; Moon, D.; Madhu, V. Reversible thermochromism of nickel(II) complexes and single-crystal-to-single-crystal transformation. ACS Omega 2019, 4, 13756–13761. doi: 10.1021/acsomega.9b01263
1. [1]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
4. [4]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
5. [5]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
6. [6]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
7. [7]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
8. [8]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
9. [9]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
10. [10]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
11. [11]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
12. [12]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
13. [13]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
14. [14]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
15. [15]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
16. [16]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
17. [17]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
18. [18]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
19. [19]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
20. [20]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(287)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142