Citation: Nan ZHANG, Yu-Hua GUO, You-Zhu YU, Zhen WANG, Yong-Sheng NIU, Xian-Li WU. Solvothermal Synthesis, Crystal Structure and Luminescence Property of a 1D Silver(I) Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2020, 39(11): 2009-2015. doi: 10.14102/j.cnki.0254–5861.2011–2750 shu

Solvothermal Synthesis, Crystal Structure and Luminescence Property of a 1D Silver(I) Coordination Polymer

a.
Henan Joint International Research Laboratory of Nanocomposite Sensing Materials, School of Chemical and Environmental Engineering, Anyang Institute of Technology, Anyang 455000, China
b.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Yong-Sheng NIU, 119yyz@163.com
Received Date: 1 February 2020
Accepted Date: 31 March 2020

Fund Project: the National Natural Science Foundation of China 21702005the Foundation of Anyang Institute of Technology YPY2019003

Figures(6)

An unprecedented one-dimensional coordination polymer [Ag₂(PhPO₃H)₂(DPPP)]_n (1) based on phenylphosphonic acid (PhPO₃H₂) and 1, 3-bis(diphenyphosphino)propane (DPPP) has been synthesized and characterized by IR, elemental analyses, thermogravimetric analyses and X-ray diffraction technique. Single-crystal X-ray diffraction analyses revealed that the complex crystallizes in triclinic system, space group P1. The coordination geometry of each Ag(I) ion is planar trigonal. Two kinds of rings were found in 1, such as the four-membered ring with Ag₂O₂ and the eight-membered ring with Ag₂O₄P₂ constructed by PhPO₃H^– ligands, which were then connected by DPPP ligands forming a zigzag type chain. Moreover, the light absorption and luminescent property of 1 were also investigated.
- silver complex,
- crystal structure,
- coordination polymer,
- photoluminescent property
1. [1]
  Zhang, J. P.; Huang, X. C.; Chen, X. M. Supramolecular isomerism in coordination polymers. Chem. Soc. Rev. 2009, 38, 2385–2396. doi: 10.1039/b900317g
2. [2]
  Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Metal carboxylates with open architectures. Angew. Chem., Int. Ed. 2004, 43, 1466–1496. doi: 10.1002/anie.200300588
3. [3]
  Tranchemontagne, D. J.; Mendoza-Cortés, J. L.; O'Keeffe, M.; Yaghi, O. M. Secondary building units, nets and bonding in the chemistry of metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1257–1283. doi: 10.1039/b817735j
4. [4]
  Liu, L. L.; Yu, Y. Z.; Zhao, X. J.; Wang, Y. R.; Cheng, F. Y.; Zhang, M. K.; Shu, J. J.; Liu, L. A robust Zn(II)/Na(I)-MOF decorated with [(OAc)₂(H₂O)₂]_n²ⁿ⁻ anions for the luminescence sensing of copper ions based on the inner filter effect. Dalton Trans. 2018, 47, 7787–7794. doi: 10.1039/C8DT00908B
5. [5]
  Yu, Y. Z.; Chang, S. Y.; Han, X.; Chen, G. X.; Xuan, Y. W.; Wu. X. L.; Wang, F. Hydrothermal syntheses, crystal structures and luminescence properties of Cu(II) and Cd(II) complexes assembled by 6-hydroxypicolinic acid and 1, 10-phenanthroline. Chin. J. Struct. Chem. 2019, 38, 651–659.
6. [6]
  Yu, Y. Z.; Chang, S. Y.; Han, X.; Chen, G. X.; Xuan, Y. W.; Wu. X. L.; Wang, F. Hydrothermal synthesis, crystal structure and luminescence property of a 2D manganese(II) coordination polymer. Chin. J. Struct. Chem. 2019, 38, 147–154.
7. [7]
  Feng, X.; Xu, C.; Wang, Z. Q.; Tang, S. F.; Fu, W. J.; Ji, B. M.; Wang, L. Y. Aerobic oxidation of alcohols and the synthesis of benzoxazoles catalyzed by a cuprocupric coordination polymer (Cu⁺-CP) assisted by TEMPO. Inorg. Chem. 2015, 54, 2088–2090. doi: 10.1021/ic502884z
8. [8]
  Wang, C.; Xie, Z.; deKrafft, K. E.; Lin, W. Facile fabrication of CdS-metal-organic framework nanocomposites with enhanced visible-light photocatalytic activity for organic transformation. J. Am. Chem. Soc. 2011, 133, 13445–13454. doi: 10.1021/ja203564w
9. [9]
  Hazra, A.; Kanoo, P.; Maji, T. K. High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework. Chem. Commun. 2011, 47, 538–540. doi: 10.1039/C0CC02490B
10. [10]
  Murray, L. J.; Dincă, M.; Long, J. R. Hydrogen storage in metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1294–1314. doi: 10.1039/b802256a
11. [11]
  Sumida, K.; Hill, M. R.; Horike, S.; Dailly, A.; Long, J. R. Synthesis and hydrogen storage properties of Be₁₂(OH)₁₂(1, 3, 5-benzenetribenzoate)₄. J. Am. Chem. Soc. 2009, 131, 15120–15121. doi: 10.1021/ja9072707
12. [12]
  Kosal, M. E.; Chou, J. H.; Wilson, S. R.; Suslick, K. S. Three-dimensional porous coordination polymer functionalized with amide groups based on tridentate ligand: selective sorption and catalysis. Nat. Mater. 2002, 1, 118–121.
13. [13]
  Li, J. R.; Kuppler, R. J.; Zhou, H. C. Selective gas adsorption and separation in metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1477–1504. doi: 10.1039/b802426j
14. [14]
  Inubushi, Y.; Horika, S.; Fukushima, T.; Akiyama, G.; Matsuda, R.; Kitagawa, S. Modification of flexible part in Cu(²⁺) interdigitated framework for CH₄/CO₂ separation. Chem. Commun. 2010, 46, 9229–9231.
15. [15]
  Banerjee, R.; Furukawa, H.; Britt, D.; Knobler, C.; O'Keeffe, M.; Yaghi, O. M. Control of pore size and functionality in isoreticular zeolitic imidazolate frameworks and their carbon dioxide selective capture properties. J. Am. Chem. Soc. 2009, 131, 3875–3877. doi: 10.1021/ja809459e
16. [16]
  Lazaro, I. A.; Forgan, R. S. Application of zirconium MOFs in drug delivery and biomedicine. Coord. Chem. Rev. 2019, 380, 230–259. doi: 10.1016/j.ccr.2018.09.009
17. [17]
  Lin, C.; Chi, B.; Xu, C.; Zhang, C.; Tian, F.; Xu, Z.; Li, L.; Whittaker, A. K.; Wang, J. Multifunctional drug carrier on the basis of 3d-4f Fe/La-MOFs for drug delivery and dual-mode imaging. J. Mater. Chem. B 2019, 7, 6612–6622.
18. [18]
  Gole, B.; Bar, A. K.; Mukherjee, P. S. Luminescent metal-organic frameworks for nitro explosives detection. Chem. Commun. 2011, 47, 12137–12139.
19. [19]
  Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. One-dimensional helical homochiral metal-organic framework built from 2, 2΄-dihydroxy-1, 1΄-binaphthyl -3, 3΄-dicarboxylic acid. Chem. Soc. Rev. 2009, 38, 1330–1352.
20. [20]
  Li, G. B.; Fang, H. C.; Cai, Y. P.; Zhou, Z. Y.; Thallapally, P. K.; Tian, J. A. Construction of a novel Zn–Ni trinuclear Schiff base and a Ni²⁺ chemosensor. Inorg. Chem. 2010, 49, 7241–7243.
21. [21]
  Dong, X. Y.; Huang, H. L.; Wang, J. Y.; Li, H. Y.; Zang, S. Q. A flexible fluorescent SCC-MOF for switchable molecule identification and temperature display. Chem. Mater. 2018, 30, 2160–2167.
22. [22]
  Xie, Y. P.; Mak, T. C. New synthesis of silver phosphonate complexes from polymeric silver phenylethynide as a structure-directing precursor. Dalton Trans. 2013, 42, 12869–12872.
23. [23]
  Adelani, P. O.; Albrecht-Schmitt, T. E. Layered uranyl coordination polymers rigidly pillared by diphosphonates. Cryst. Growth Des. 2012, 12, 5800–5805.
24. [24]
  Guo, L. R.; Tong, J. W.; Liang, X.; Köhler, J.; Nuss, J.; Li, Y. Z.; Zheng, L. M. Silver(I) pyrophosphonates: structural, photoluminescent and thermal expansion studies. Dalton Trans. 2011, 40, 6392–6400.
25. [25]
  Singleton, R.; Bye, J.; Dyson, J.; Baker, G.; Ranson, R. M.; Hix, G. B. Tailoring the photoluminescence properties of transition metal phosphonates. Dalton Trans. 2010, 39, 6024–6030.
26. [26]
  Yu, Y. Z.; Guo, Y.; Zhang, Y. R.; Liu, M. M.; Feng, Y. R.; Geng, C. H.; Zhang, X. M. A series of silver doped butterfly-like Ti₈Ag₂ clusters with two Ag ions panelled on a Ti₈ surface. Dalton Trans. 2019, 48, 13423–13429.
27. [27]
  Sheldrick, G. M. SHELXS-97. Program for the Solution of Crystal Structure. University of Göttingen, Germany 1997.
28. [28]
  Sheldrick, G. M. SHELXL-97. Program for the Refinement of Crystal Structure. University of Göttingen, Germany 1997.
29. [29]
  Li, X. Y.; Yin, T. Q.; Wang, C. Y.; Zhang, J.; Wang, Y.; Gao, L.; Hu, B.; Liu, B.; Jiang, W.; Che, G. B. Synthesis, crystal structure and theoretical calculation of a novel 2D network of manganese(II) complex. Chin. J. Struct. Chem. 2019, 38, 2113–2120.
30. [30]
  Ma, K. R.; Zhang, Y.; Kan, Y. H.; Li, R. Q.; Hu, H. Y. Syntheses, structures and fluorescent properties of three low-dimensional Zn^II-diphosphonate coordination polymers. Chin. J. Inorg. Chem. 2014, 30, 2549–2558.
31. [31]
  Huang, J. L.; Bao, Z. Y. The Ultraviolet Absorption Spectrometry and Its Application. China Science and Technology Press: Beijing 1992.
32. [32]
  Wang, J. J.; Yu, Y. Z.; Wang, E. N.; Jin, F.; Zhang, M. Y.; Zhao, Q. Q.; Huang, H. N. Inorganic-acid-induced structures of cobalt(II) and copper(II) complexes based on 2, 4, 5-tri(4-pyridyl)- imidazole ligand. Inorg. Nano-Met. Chem. 2017, 47, 1590–1598.
33. [33]
  Jiang, W.; Yang, J.; Yan, G.; Zhou, S.; Liu, B.; Qiao, Y.; Zhou, T.; Wang, J.; Che, G. A novel 3-fold interpenetrated dia metal-organic framework as a heterogeneous catalyst for CO₂ cycloaddition. Inorg. Chem. Commun. 2020, 107770.
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