Citation: Wei LI, Gang PENG, Hua LAI, Geng HUANG, Chang-Hong LI. Hydrothermal Synthesis, Crystal Structure and Luminescence Property of a New Binuclear Cage-like Samarium(Ⅲ) Complex Sm₂(C₇H₄ClCOO)₆(C₁₂H₈N₂)₂(H₂O)₂[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 350-355. doi: 10.14102/j.cnki.0254–5861.2011–2481 shu

Hydrothermal Synthesis, Crystal Structure and Luminescence Property of a New Binuclear Cage-like Samarium(Ⅲ) Complex Sm₂(C₇H₄ClCOO)₆(C₁₂H₈N₂)₂(H₂O)₂

Wei LI ^{a, c,,} ,
Gang PENG ^a ,
Hua LAI ^a ,
Geng HUANG ^a ,
Chang-Hong LI ^b,,

a.
School of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China
b.
School of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421002, China
c.
Key Laboratory of Functional Metal-organic Compounds of Hunan Province Hengyang, Hengyang, Hunan 421008, China

Corresponding author: Wei LI, li_weihnxy@163.com Chang-Hong LI, lichanghong4444@126.com
Received Date: 31 May 2019
Accepted Date: 3 July 2019

Fund Project: the Natural Science Foundation of Hunan Province 2019JJ60021the Natural Science Foundation of Hunan Province 2019JJ50013the Scientific Research Found of Hunan Provincial Education Department of China 17A049the Scientific Research Found of Hunan Provincial Education Department of China 16C0224the Industry and Research Key Project of Hengyang City 2018kKJ016the Industry and Research Key Project of Hengyang City 2017KJ155the Industry and Research Key Project of Hengyang City 2017KJ193

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A new binuclear cage-like samarium(Ⅲ) complex Sm₂(C₇H₄ClCOO)₆(C₁₂H₈N₂)₂(H₂O)₂ (1) with samarium(Ⅲ) nitrate, m-chlorobenzoic acid and 1, 10-phenanthroline(phen) was synthe-sized. It crystallizes in the triclinic space group P\begin{document}$ \overline 1 $\end{document}, with a = 8.0217(2), b = 12.9037(4), c = 15.3764(5) Å, α = 85.373(3)º, β = 84.396(3)º, γ = 80.443(3)º, V = 1558.64(8) Å³, D_c = 1.636 g/cm³, Z = 2, F(000) = 806, the final GOOF = 1.051, R = 0.0754 and wR = 0.1388. The whole molecule consists of two samarium ions bridged by four m-chlorobenzoic acid anions. The Sm(Ⅲ) ion is coordinated by eight atoms to give a distorted square antiprism coordination geometry. The TG analysis and fluorescent properties of 1 were studied.
- binuclear samarium(Ⅲ) complex,
- thermal stability,
- fluorescent property
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Hydrothermal Synthesis, Crystal Structure and Luminescence Property of a New Binuclear Cage-like Samarium(Ⅲ) Complex Sm2(C7H4ClCOO)6(C12H8N2)2(H2O)2

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis, Crystal Structure and Luminescence Property of a New Binuclear Cage-like Samarium(Ⅲ) Complex Sm₂(C₇H₄ClCOO)₆(C₁₂H₈N₂)₂(H₂O)₂